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Citation: Liu Peng, Zeng Rong, Gao Zhen, Zhu Qi-He. Reaction of Silver and Sulfur Clusters[J]. Acta Physico-Chimica Sinica, ;2000, 16(01): 93-95. doi: 10.3866/PKU.WHXB20000118 shu

Reaction of Silver and Sulfur Clusters

1.
State Key Laboratory of Molecular Rection Dynamics,Institute of Chemistry,Chinese Academy of Scinences,Beijing 100080

Received Date: 22 March 1999
Available Online: 15 January 2000

The reaction of silver and sulfur clusters was studied with Laser Double Ablation Reactor-Tandem TOF MS, and [AgS4]+, [AgS8] +, [AgS12] + and [AgS16] + were detected as the main products. The 193nm laser photodissociation of [AgS12] +. and [AgS16] + gave mainly [AgS4] + and [AgS8] + respectively. Photodissociation products of [AgS8]+ were Ag+, [AgS2] + and [AgS4] +, and that of [AgS4] + was not detected. We also discussed the possible mechanism of the reactions forming Products [AgS12 ] + and [AgS16] +.
- Cluster,
- Reaction,
- Laser ablation
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