Citation: Ouyang Jian-Ming, Tai Zi-Hou, Tang Wen-Xia. XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal Ions[J]. Acta Physico-Chimica Sinica, ;1998, 14(01): 84-87. doi: 10.3866/PKU.WHXB19980116
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The complex formation of 2-hexadecylcarbamoyl-8-hydroxyquinoline(HHQ) monolayers at the air/water interface by reaction with metal ions from the subphase was investigated using X-ray photoelectron spectroscopy. The formation of HHQ-metal complexes leads to the appearance of new peaks assigned to the metal ions. The information on stoichimoetry provided by XPS indicated that a metal ion is coordinated by two HHQ molecules for La3+ and Cd2+ ions, but by one HHQ molecule for Mn2+ and Ni2+ ions.
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