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Citation: Zou Peng, Wu Guo-Sheng, Chen Wen-Wu, Yang Da-Lin, Sheng Liu-Si, Wu Guo-Hua, Ye Wei-Quan, Zhang Yun-Wu. A Study of 1,4-dioxane Photoionization and Dissociation[J]. Acta Physico-Chimica Sinica, ;1998, 14(01): 21-26. doi: 10.3866/PKU.WHXB19980105 shu

A Study of 1,4-dioxane Photoionization and Dissociation

1.
The State Key Laboratory of Molecular Reaction Dynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080

Received Date: 9 April 1997
Available Online: 15 January 1998

The photoionization-dissociation pattern of 1,4-dioxane has been studied by molecular beam. VUV from Synchrotron Radiation and TOF mass spectrometry. The possible fragmentation channel and structures of ion fragments(m/e 41 28 29 58 57)have been discussed on the basis of PIE curves, and a rearrangement reaction mechanism for the photoionization-dissociation of 1,4-dioxane has been proposed.
- 1,4-dioxne,
- Synchrotron radiation,
- Photoionization and dissociation,
- Rearrangement reaction
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