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Citation: Luo Ren-Sheng, Yan Jiang-Li, Mao Xi-An. Study of Ligand Exchange Kinetics for Sn(IV) Complex Using 2D NMR[J]. Acta Physico-Chimica Sinica, ;1997, 13(10): 925-928. doi: 10.3866/PKU.WHXB19971012 shu

Study of Ligand Exchange Kinetics for Sn(IV) Complex Using 2D NMR

1.
State Key Laboratoy of Magnetic Resonance and Atomic Molecular Physics,Wuhan Institute of Physics,Chinese Academy of Sciences,Wuhan 430071

Received Date: 2 December 1997
Available Online: 15 October 1997

Two-dimensional 1H exchange spectroscopy was applied to study of the ligand exchange kinetics of the complex [Sn2(μ-OH)2Cl6(DMF)2]•4DMF in DMF-d7 solution. The exchange rate constants for the ligand H2O and DMF between free and coordination states were evaluated.
- Sn(IV) complex,
- 2D EXSY,
- Exchange rate constants
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