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Citation: Li Li, He Tian-Jing, Wang Xiu-Yan, Liu Fan-Zhen. ESR Shift Induced by a Circularly Polarized Laser Beam and Antisymmetric Polarizability of [IrBr₆]^2-[J]. Acta Physico-Chimica Sinica, ;1997, 13(08): 685-692. doi: 10.3866/PKU.WHXB19970803 shu

ESR Shift Induced by a Circularly Polarized Laser Beam and Antisymmetric Polarizability of [IrBr₆]^2-

1.
Department of Chemical Physics and Structure Research Laboratory,University of Science and Technology of China,Hefei 230026

Received Date: 9 December 1996
Available Online: 15 August 1997

This paper studies theoretically the effect of circularly polarized laser on ESR spectra in a spin specie system. The antisymmetric polarizability and the laser-induced ESR shift (Δv -- Δv+) of the complex [IrBr6]2- were calculated. The influence of the width г of the absorption line on the ESR shift was discussed. The results show that the ESR shift can be as large as 1MHz order of magnitude at a frequency near optical absorption, which is similar to that of the sodium atom.
- Antisymmetric polarizability,
- Laser-induced ESR shift,
- Transition metal complex [IrBr₆]^2-
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ESR Shift Induced by a Circularly Polarized Laser Beam and Antisymmetric Polarizability of [IrBr6]2-

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通讯作者: 陈斌, bchen63@163.com

ESR Shift Induced by a Circularly Polarized Laser Beam and Antisymmetric Polarizability of [IrBr₆]^2-