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Citation: Lin Hua-Kuan, Zhu Shou-Rong, Kou Fu-Ping, Chen Rong-Ti. Study on Stability of Copper(II)-5-Substituted-1,10-Phenanthrolines-Dioxotraamines Macrocycles Ternary Systems[J]. Acta Physico-Chimica Sinica, ;1997, 13(05): 417-424. doi: 10.3866/PKU.WHXB19970507 shu

Study on Stability of Copper(II)-5-Substituted-1,10-Phenanthrolines-Dioxotraamines Macrocycles Ternary Systems

1.
Department of Chemistry,Nankai University,Tianjin 300071

Received Date: 7 October 1996
Available Online: 15 May 1997

The stability of copper (Ⅱ)-13-(2'-Hydroxy-3',5'-substituted benzyl)-1,4,8,11-tetraazacyclotetradecane-12, 14-dione(RTADO-14) binary complex compounds and of copper (Ⅱ)-5-substituted-1,10-phenanthrolines(R'TADO)-RTADO-14 ternary complex compounds was studied by means of pH titration method at 25.0±0.1 ℃ and I=0.1mol?dm-3KNO3. The formation constants of binary and ternary complexes were obtained. The structures of the binary and ternary complxes and the effects fo substituents on macrocyclic ligands and on R'Phen were also discussed.
- Stability of complexes,
- Functionalized macrocyclic dioxotetraamines,
- 5-Substituted-1,10-phenanthrolines,
- Copper(II)
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