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Citation: Sun Da-Yong, Liu Zi-Yang, Guo Xing-Hua, Xu Wen-Guo, Ji Yi-Ping, Liu Shu-Ying. High-Yield Synthesis and Extraction of Gd@ C_2n[J]. Acta Physico-Chimica Sinica, ;1996, 12(10): 873-875. doi: 10.3866/PKU.WHXB19961003 shu

High-Yield Synthesis and Extraction of Gd@ C_2n

1.
The Key Laboratory of Applied Spectroscopy,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022

Received Date: 24 June 1996
Available Online: 15 October 1996

Endohedral metallofullerene Gd@C2n were synthesized with high-yield using the carbon-arc discharge method of activating the Gd2O3-containing graphite anode in situ and back-burning technique. A series of Cd@C(2n) for 2n from 70 to 96 were effectively extracted by toluene at high-temperature and under high-pressure condition. Gd@C(82), Gd@C(74) were considered to be fairly stable and soluble metallofullerene species.
- Fullerene,
- Metallofullerenes,
- Gd@ C_2n
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沈阳化工大学材料科学与工程学院沈阳 110142

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High-Yield Synthesis and Extraction of Gd@ C_2n