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Citation: Zhu Xiao-Lei, Zhou Zhi-Hua, Xu Yong-Jin, Zhou Yao-Ming. Investigation on Dipole-dipole Interaction(II)[J]. Acta Physico-Chimica Sinica, ;1996, 12(04): 365-367. doi: 10.3866/PKU.WHXB19960416 shu

Investigation on Dipole-dipole Interaction(II)

1.
Department of Chemistry,Nanjing Normal University,Nanjing 210097

Received Date: 19 June 1995
Available Online: 15 April 1996

The coherent potential approximation (CPA) was used in the calculation of the vibrational spectra for absorbed 12CO/13CO mixtures on platinum. The theoretical results were compared with the surface IR-spectra of 12CO/13CO mixture absorbed on Pt-electrode. The results show that in the systems consisting of isotopic mixtures of CO on Pt(001), molecules interact mainly through their dipole fields.
- Dipole-dipole interaction,
- Coherent potential approximation,
- Intensity transfer,
- Frequency shift
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