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Citation: Cao Yang, Zhu Zhi-Dong, Zhao Bo. Determination of Second-order Polarizabilities of BMC and MMONS by Solvatochromic Method[J]. Acta Physico-Chimica Sinica, ;1995, 11(04): 356-359. doi: 10.3866/PKU.WHXB19950414 shu

Determination of Second-order Polarizabilities of BMC and MMONS by Solvatochromic Method

1.
Department of Chemistry,Suzhou University,Suzhou 215006

Received Date: 3 January 1994
Available Online: 15 April 1995

Second-order polarizabilities of BMC and MMONS were determined by solvatochromic method. The second-order polarizabilities of BMC and MMONS were also calculated by quantum chemical semiempirical CNDO/S-CI method and perturbation theory and second-order nonlinear optical data respectively. Calculated values are in od agreement with experimental results. The effect of molecular and crystal structure on second-order polarizabilities has also been discussed.
- Second-order polarizabilities,
- Solvatochromic method,
- Double frequency effect
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