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Citation: Hao Ai-You, Tong Lin-Hui, Gao Xing-Ming, Zhang Fu-Sheng. Studies for the Molecular Recognition Abilities of β-Naphthoated β-Cyclodextrin(β-CD) Derivatives[J]. Acta Physico-Chimica Sinica, ;1995, 11(03): 202-205. doi: 10.3866/PKU.WHXB19950304 shu

Studies for the Molecular Recognition Abilities of β-Naphthoated β-Cyclodextrin(β-CD) Derivatives

1.
Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000

Received Date: 18 November 1994
Available Online: 15 March 1995

The molecular recognition abilities of β-naphthoated β-CD derivatives as the host compounds were studied: 3-o-β-Naphthoyl-β-CD has a largely improved association constant with cyclohexanol than the corresponding 6-position substituted β-CD derivative has. On the other hand, the polarisablity and the sturcture of the gueset molecule are also important factors which affect the association constant. Cyclohexane may form the 1:2 type inclusion compound with the host compound in this report.
- β-Naphthoated β-CD derivatives,
- Host-Guest chemistry,
- Molecular recognition,
- Difference ultraviolet spectrum
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