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Citation: Hu Chang-Wen, He Qing-Lin, Tang Tian-Di, Wang En-Bo. Study on the Synthesis,Characterization and Catalysis of Pillared Anion Clay(II)[J]. Acta Physico-Chimica Sinica, ;1995, 11(03): 193-195. doi: 10.3866/PKU.WHXB19950301 shu

Study on the Synthesis,Characterization and Catalysis of Pillared Anion Clay(II)

1.
Department of Chemistry,Northeast Normal University,Changchun 130024

Received Date: 18 October 1994
Available Online: 15 March 1995

Layered double hydrotalcites pillared by heteropolyoxometates, ZnAl- GeW11Z (Z=Ni2+, Cu2+) and ZnAl-GeW11 have been synthesized by ion exchange. A procedure for intercalating layered double hydroxides is described in this paper, powder X-ray diffraction and IR spectra measurements confirm that for GeW11O39Z (H2O)6- and GeW11O398- intercalation takes place and the gallery heights are of 9.9Å. The new compounds are found to be calalytically efficient for the esterification of acetic acid with n-butanol in liquid-phase.
- Transition element,
- Heteropolyoxometales,
- Clays,
- Esterification activity
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