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Citation: Sun Qi, Gu Yue-Shu, Guo Jing-Zhong, Yin Yong-Jia, Li Xue-Chu, Shen Guan-Lin. Energy Transfer Reactions of Ar(³P_0.2)与SO₂,SOCl₂ under the Single Collision Condition[J]. Acta Physico-Chimica Sinica, ;1995, 11(01): 31-37. doi: 10.3866/PKU.WHXB19950107 shu

Energy Transfer Reactions of Ar(³P_0.2)与SO₂,SOCl₂ under the Single Collision Condition

1.
Chemistry Department

Received Date: 4 October 1993
Available Online: 15 January 1995

Dissociative excitation of SO2,SOCl2 through single collision with Ar(3P0,2)have been studied by observing SO(A - X) emission in the beam apparatus. The nascent vibrational distribution of SO(A, υ＇) was determined. A Surprisal analysis of the nascent vibrational distribution of SO(A) indicated that the precursor molecules dissociation could occur predominately from superexcited states (Rydberg-states). The formation rate constants of SO(A) have been determined for Ar(3P0,2)/SO2 and Ar(3P0,2)/SOCl2 reactions, They are: 4．55×10－12cm3•molecule－1•s－1 and 2．87×10－12cm3•molecule－1•s－1, respectively. A comparison between the observed formation rate constants and known total quenching rate constants indicated that dissociative excitation processes are monitor exit channels.
- Metastable atom,
- Dissociative excitation,
- Vibrational distribution,
- Reaction channel
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Energy Transfer Reactions of Ar(3P0.2)与SO2,SOCl2 under the Single Collision Condition

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通讯作者: 陈斌, bchen63@163.com

Energy Transfer Reactions of Ar(³P_0.2)与SO₂,SOCl₂ under the Single Collision Condition