Citation:
Li Chun-Guang, Cui Gang. Synthese and Properties of Electrochemical of [CuCl3CPZ(O)H] Complex[J]. Acta Physico-Chimica Sinica,
;1994, 10(08): 755-758.
doi:
10.3866/PKU.WHXB19940818
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CPZ(O)HCl was synthesized by oxdation of 2-clilorcr-10-(3- dimethylaminopropyl) phenothiazime hydrochloride (CPZHCl) and reacted with CuCl2 to produce [CuCl3CPZ(O)H] complex. The properties of electrochemical of [CuCl3CPZ(O)H] were studies by cyclic voltammetry and conductivity method. The reaction of [CuCl3CPZ(O)H] complex on GC electrode shows single electron reaction and order of magnitude of k 10-4cm.s-1. Molal conductivities of [Cu(Ⅱ)Cl3CPZ(O)H] and CPZ(O)HCl are 220-122S.cm2 .mol-1 and 150-48S'cm2 .mol-1.
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