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Citation: Zhang Wei-De, Zhan Rui-Yun, Ye Xing-Kai, Wu Yue. Preparation of SiO₂-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen[J]. Acta Physico-Chimica Sinica, ;1994, 10(07): 654-657. doi: 10.3866/PKU.WHXB19940715 shu

Preparation of SiO₂-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen

1.
Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Received Date: 13 February 1993
Available Online: 15 July 1994

The metal phthalocyanines (MPc, M=Fe, Co, Cu) were supported on the surface of silica gel by chemical linking. They could not be washed out with organic solvents such as Py. UV-Vis diffuse reflectance spectra indicated that MPc s were supported on silica gel. ESR result showed that the supported CoPc and FePc could react with O_2 to produce O~-_2, but the supported CuPc could not.
- Metal phthalocyanine,
- Supported; The activation of O₂,
- Catalyst
  ,
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沈阳化工大学材料科学与工程学院沈阳 110142

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Preparation of SiO2-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen

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通讯作者: 陈斌, bchen63@163.com

Preparation of SiO₂-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen