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Citation: Zheng Ji-Min, Che Yun-Xia, Wang Ru-Ji, Wang Hong-Gen. Crystal Structure of 1:1 Adduct of Glycine and m-nitrobenzoic Acid[J]. Acta Physico-Chimica Sinica, ;1994, 10(01): 64-68. doi: 10.3866/PKU.WHXB19940115 shu

Crystal Structure of 1:1 Adduct of Glycine and m-nitrobenzoic Acid

1.
Department of Chemistry, Nankai University, Tianjin 300071

Received Date: 3 June 1992
Available Online: 15 January 1994

The title 1:1 adduct, has been prepared and a large single crystal with dimensions of 5 mm×50 mm×20 mm was obtained by slow-cooling method. It produces the green radiation at 532 nm under the irradiation of Nd~3+: YAG laser beam at 1064nm. The crystal structure of this potential non-linear optical material was determined by X-ray diffraction method. The crystal is orthorbombic, space group Pca2_1, with a=2.2701(5) nm, b=0.5852(2) nm, c=0.7815(2) nm, Z=4; final R is 0.054 for 702 observed reflections. The intermolecular hydrogen bonds are formed between the amino and carboxyl groups of glycines, which connect the glycine molecules to form two-dimensional network parallel to the (100) plane, while the intermolecular hydrogen bonds between the carboxyl group of glycine and the carboxyl group of m-nitrobenzoic acid let the latter link to above mentioned two-dimensional network.
- Non-linear optical meterial,
- Crystal structure,
- Adduct of glycine and m-mitrobenzoic acid
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