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Citation: Zhuang Hong-Hui, Wu Ding-Ming, Lu Can-Zhong, Tong Wen. Synthesis and Crystal Structure of (C₅H₇S₂)₂[Cu₃I₅][J]. Acta Physico-Chimica Sinica, ;1993, 9(04): 548-552. doi: 10.3866/PKU.WHXB19930423 shu

Synthesis and Crystal Structure of (C₅H₇S₂)₂[Cu₃I₅]

1.
Fujian Institute of Research on the Structure of Matter, Euzhou Laboratory of Structural Chemistry, Chinese Academy of Science, Fuzhou 350002

Received Date: 3 February 1992
Available Online: 15 August 1993

The crystal structure of the title compound has been determined from single-crystal X-ray diffractometer data. (C_5H_7S_2)_2[Cu_3I_5] crystallizes in space group I 2/a with α=1.8126(12), b=0.9302(2), c=1.4275(2)nm, β=101.51(1)°and z= 4. The full-matrix least-squares refinement gave R=0.043 for 1820 observed [I>3.0σ(I)] reflections. The crystal structure consists of (C_5H_7S_2) cations and [Cu_3I_5]_∞ anions of infinite I-bridged chains, the repeat unit of which contains one three-coordinated copper(I) atom, the ligand configuration being approximatively tri nal planar, and two four-coordinated copper(I) atoms, possessing the ligand configuration of tetrahedron. The Cu—Cu distances are 0.2528(2) and 0.2557(2) nm, respectively.
- Cu-I infinit chain of anion; Crystal structure
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Synthesis and Crystal Structure of (C5H7S2)2[Cu3I5]

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Crystal Structure of (C₅H₇S₂)₂[Cu₃I₅]