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Citation: Xia Xu-Bing, Duan Chun-Ying, Zhu Long-Gen, Cao Hong, You Jing-Jing. Study on the Ferrocene-Containing Ploynuculi Metal Complexes Quenching Luminescence of ^*[Cr(bpy)₃]³⁺[J]. Acta Physico-Chimica Sinica, ;1993, 9(02): 268-272. doi: 10.3866/PKU.WHXB19930224 shu

Study on the Ferrocene-Containing Ploynuculi Metal Complexes Quenching Luminescence of ^*[Cr(bpy)₃]³⁺

1.
Coordination Chemistry Institute, Nanjing University, Nanjing 210008; Food Frementation Institute of Jiangsu, Nanjing 210024

Received Date: 15 November 1991
Available Online: 15 April 1993

Ferrocene-containing ploynuclear metal complexes M(Fe-C(CH_3)=N N=CSSR)_2 (M=Ni~(2+), Cu~(2+), Zn~(2+), Pd~(2+), Co~(2+), Cd~(2+), R=CH_3, CH_2φ) have been synthesized and characterized by cyclic voltummetry. It has been found that this kind of complexes can quench the luminescence of [Cr(bpy)_3]~(3+) efficiencily. The Stern-Volmer plot is linear and yield the bimolecular quenching rate constants in order of 10~8～10~9 dm~3·mol~(-1)·s~(-1). The quenching process is carrid out through electron transfer and energy transfer mechanism.
- Cr(bpy)³⁺₃; Polynuclear complexes; Quenching process; Electron and energy transfer mechanisms
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Study on the Ferrocene-Containing Ploynuculi Metal Complexes Quenching Luminescence of ^*[Cr(bpy)₃]³⁺