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Citation: Wu Bing-Fang, Yan Xiu-Ying, Liu Qi-Wang, Liu Shu-Tang, Hu Xiang. Synthesis and Crystal Structure of Cluster (μ-SC₆H₅)(μ-P(SC₆H₅)₂)Fe₂(CO)₆[J]. Acta Physico-Chimica Sinica, ;1992, 8(06): 749-752. doi: 10.3866/PKU.WHXB19920607 shu

Synthesis and Crystal Structure of Cluster (μ-SC₆H₅)(μ-P(SC₆H₅)₂)Fe₂(CO)₆

1.
Department of Chemistry, Nei Monggu University, Huhehot 010021

Received Date: 26 July 1991
Available Online: 15 December 1992

The title compound was obtained by the reaction of Fe_3(CO)_(12) with phosphorotri-thious acid triphenyl ester P(SC_6H_5)_3. Ligand precursor P(SC_6H_5)_3 coordinated to the cluster by its cleaved fragments SC_6H_5 and P(SC_6H_5)_2. The crystal structure of the compound has been determined by a single crystal X-ray diffraction method. The crystal is orthorhombic, space group belongs Pbca, a=1.7422(7), b=1.0634(6), c=2.8987(12) nm; V=5.370 nm, z=8, D_c=1. 579 g·cm~(-3). Coordinates of all nonhydrogen atoms were delermined by idrect method and difference Fourier synthesis, with 3531 observable reflections (I≥3σ(I_0)) refined by a full-matrix least-squares procedure so that the final R=0.054, R_W=0.058. The dihedral angle of the folded Fe_2SP ring along the S…P line or the Fe—Fe bond (76.1° or 82°, respectively) is much smaller than that for other similar compounds with the central Fe_2S_2 or Fe_2P_2 or Fe_2·SP folded rings. Fe—Fe=0.2572(2) nm, Fe—S(1)—Fe=68.6°(1), Fe—P—Fe=70.7°(1).
- Dinuclear iron carbonyl derivative; Synthesis; Crystal structure; Bridging atom
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Synthesis and Crystal Structure of Cluster (μ-SC₆H₅)(μ-P(SC₆H₅)₂)Fe₂(CO)₆