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Citation: Wang Jian-Jun, Wang Xiao-Chun, Ouyang Yi-Shan, You Yu-Jian, Dai An-Bang. The Solution Structure Studies of L-Lysine by Means of NMR Lanthanide Shift Reagent[J]. Acta Physico-Chimica Sinica, ;1992, 8(05): 647-653. doi: 10.3866/PKU.WHXB19920514 shu

The Solution Structure Studies of L-Lysine by Means of NMR Lanthanide Shift Reagent

1.
Medical College, Nanjing University, Nanjing 210008; Department of Chemistry, Nanjing Univeristy, Nanjing 210008

Received Date: 14 August 1990
Available Online: 15 October 1992

~(13)C NMR spectral studies have been performed on the structure of the adducts of lanthanide ions and L-lysine using aqueous lanthanide shift reagents. The lanthanide-induced shifts are separated into contact and dipolar components by a new method of separation with a self-consistent manner. The geometry of L-lysine is described by the geometric factors derived from dipolar shifts, optimized by computer search, and checked by Euler transformation.
- L-lysine; Structure; Lanthanide shift reagent; ¹³C-NMR
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