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Citation: Zhu Wen-Xiang, Zhao Ji-Zhou, Yang Rui-Na, Huang Hui-Zhong. Investigation on XPS of Lanthanide Complexes of Crown Ethers[J]. Acta Physico-Chimica Sinica, ;1991, 7(03): 371-374. doi: 10.3866/PKU.WHXB19910323 shu

Investigation on XPS of Lanthanide Complexes of Crown Ethers

1.
Department of Chemistry, Beijing Normal University, Beijing 100875; Institute of Physical Chemistry, Peking University, Beijing

Received Date: 30 December 1989
Available Online: 15 June 1991

Binding energies of Ln 3d_(5/2) of Rare Earths and N_(1S), O_(1S) of ligands in two series of lanthanide complexes of RE(NO_3)_3·C_(12)H_(22)O_4 and Ln(NO_3)_3·2H_2O·bipy·B-15-C-5 have been measured. Shake down satellite peaks for lanthanide ions have also been detected. The character of coordination bonds is discussed based on the satellite phenomena.
- RE(NO₃)₃•C₁₂H₂₂O₄(RE=La-Er,Y); Ln(NO₃)₃•bipy•2H₂O•B-15-C-5(Ln=La-Eu); Lanthanide complexes; XPS
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