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Citation: Jiang Yun-Bao, Huang Xian-Zhi, Chen Guo-Zhen. A Study of the Interaction of Aliphatic Alcohol with β-Cyclodextrin by Fluorescence and Absorption Spectroscopies[J]. Acta Physico-Chimica Sinica, ;1991, 7(03): 289-293. doi: 10.3866/PKU.WHXB19910306 shu

A Study of the Interaction of Aliphatic Alcohol with β-Cyclodextrin by Fluorescence and Absorption Spectroscopies

1.
Department of Chemistry, Xiamen University, Xiamen 361005

Received Date: 25 February 1990
Available Online: 15 June 1991

Pyrene was used as a spectral probe in studying the interaction of some watersoluble aliphatic alcohols with β-cyclodextrin (β-CD) by fluorescence and absorption spectroseopies. Results showed that monobasic alcohol can decrease the micropolarity of β-CD cavity, but the formation constant of pyrene-β-CD inclusion complex is being larger, and polybasie alcohol had the opposite effects. The hydrogen-bonding interaction between alcohols and β-CD was proposed to explain the results.
- Aliphatic alcohols; β-Cyelodextrin; Fluorescence and Absorption Spectroscopies
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