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Citation: Bian Ze-Liang, Zhang Qi-Yuan, Sun Xiang-Yu, Zhao Yao-Xing. Investigation of Fast Atom Bombardment Mass Spectrometry of Arenediazonium Salts/Mechanism of Their Quasi-Molecular Ions[J]. Acta Physico-Chimica Sinica, ;1991, 7(02): 219-222. doi: 10.3866/PKU.WHXB19910218 shu

Investigation of Fast Atom Bombardment Mass Spectrometry of Arenediazonium Salts/Mechanism of Their Quasi-Molecular Ions

1.
National Laboratory for Structural Chemistry of University and State Species, Beijing 100080; Institute of Chemistry, Academia Sinica, Beijing

Received Date: 28 November 1989
Available Online: 15 April 1991

Fast atom bombardment mass spectra of a series of arenediazonium salts with various substituents complexed with 18-crown-6 and dibenzo-24-crown-8 ethers were examined. The correlation between quasi-molecular ion abundance of various complexes and the properties, coordination ability of donor-acceptor linkages in the complexes were studied. By using molecular orbital calculation we have successfully demonstrated that the correlation cited is related to the electron cloud densities on the heteroatoms α-N and β-N of arenediazonium salts.
- Arenediazonium salts; Crown ethers complexs; Fast atom bombardment mass spectrometry
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