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Citation: Liu Shu-Tang, Liu Qi-Wang, Wu Bin-Fang, Suo Quan-Ling, Hu Xiang, Wang Be-Yi. SYNTHESIS AND CRYSTAL STRUCTURE OF Fe₃(CO)₈[P[SC₆H₅)Cl₂](μ₃-S)₂[J]. Acta Physico-Chimica Sinica, ;1990, 6(06): 730-734. doi: 10.3866/PKU.WHXB19900618 shu

SYNTHESIS AND CRYSTAL STRUCTURE OF Fe₃(CO)₈[P[SC₆H₅)Cl₂](μ₃-S)₂

1.
Department of Chemistry; Nei Monggu University; Hohhot Center of Analysis and Measurement; Fudan University

Received Date: 31 May 1989
Available Online: 15 December 1990

The title compound Fe_3(CO)_8 (P(SC_6H_5) Cl_2) (μ_3′-S)_2 was synthesised by reacting Fe_3(CO)_9 (μ_3-S)_2 with P (SC_6H_5) Cl_2.
The crystal and molecular structure of the title compound has been determined by single crystal diffraction method. Crystal data: triclinic, space group P1, with a=0.7571(1), b=0.9097(1), c=1.7706(2) nm, α=95.03(1), β=101.79(1), γ=105.73(1)°, V =1.1359 nm, Z=2, Dc=1.935 g·cm~(-3). The structure was solved by direct method and difference Fourier synthesis, and refined by full-matrix least-squares with anisotropic thermal paramaters for non-hydrogen atoms, using 3724 observed reflections withI≥3σ(I). The final residual factor R=0.025, R_W=0.028.
Fe_(CO)_8(P(SC_6H_5)Cl_2)(μ_3-s)_2 has a face-bridged 4e donors and the monosubstituted ligand is on the apical Fe atom.
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SYNTHESIS AND CRYSTAL STRUCTURE OF Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2

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SYNTHESIS AND CRYSTAL STRUCTURE OF Fe₃(CO)₈[P[SC₆H₅)Cl₂](μ₃-S)₂