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Citation: Yang Hui-Xing, Cui Xiao-Li, Lu Qun, Han De-Gang. Study of Kinetics and Mechanism for The Reaction Between Molybdenum(v) Tetraphenylporphyrine (Mo^vO(TPP)Cl) and Dimethyl Sulfoxide (DMSO)[J]. Acta Physico-Chimica Sinica, ;1990, 6(05): 594-600. doi: 10.3866/PKU.WHXB19900515 shu

Study of Kinetics and Mechanism for The Reaction Between Molybdenum(v) Tetraphenylporphyrine (Mo^vO(TPP)Cl) and Dimethyl Sulfoxide (DMSO)

1.
Department of Chemistry, Peking University, Beijing

Received Date: 19 January 1989
Available Online: 15 October 1990

The kinetics of the reaction of MovO(TPP)Cl and DMSO has been studied with a stopped-flow spectrophotometer. The results show that the reaction is a complicate one which includes at least four elementary steps. The relaxation time (τ) varies linearly with the initial concentrations of DMSO. A reaction mechanism was suggested which can explain the experimental results satisfactorily.
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Study of Kinetics and Mechanism for The Reaction Between Molybdenum(v) Tetraphenylporphyrine (MovO(TPP)Cl) and Dimethyl Sulfoxide (DMSO)

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通讯作者: 陈斌, bchen63@163.com

Study of Kinetics and Mechanism for The Reaction Between Molybdenum(v) Tetraphenylporphyrine (Mo^vO(TPP)Cl) and Dimethyl Sulfoxide (DMSO)