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Citation: Su Wen-Duan, Zhou Xiao-Lin. Statistical Mechanical Treatment of Absorbed Monolayer at Electrode/Solution Interface I. The Inner-layer Differential Capacity for Mercury Electrode in Non-aqueous Solution[J]. Acta Physico-Chimica Sinica, ;1990, 6(05): 568-574. doi: 10.3866/PKU.WHXB19900511 shu

Statistical Mechanical Treatment of Absorbed Monolayer at Electrode/Solution Interface I. The Inner-layer Differential Capacity for Mercury Electrode in Non-aqueous Solution

1.
Department of Chemistry, Xiamen University; Computer Center, Xiamen University

Received Date: 24 January 1989
Available Online: 15 October 1990

A model of dipole orientation distribution for solvate layer at electrode/solution interface was suggested, and based on this model a generalized monolayer adsorption isotherm was derived by using the method of statistical mechanics and assuming the equilibrium condition of thermodynamics. The solvent of the electrolyte studied may be single component or multic-components (mixture). The dependence of inner-layer differential capacity upon snrface charge density at mercury electrode in formamide, methanol and ethylene carbonate solutions was estimated by curve-fitting respectively. The present model is more suitable for aqueous and mixed-solvent systems will be expected.
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