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Citation: Chen Feng-Xiang, Zhu Wen-Jie, Li Neng, Lin Bing-Xiong, Tang You-Qi, Feng Qing-Rong, Wu Ke, Xue Li-Xin, Zhong Shan-Jin, He Jun. Effects of High Valence Cations Doped on the Phase Formation and the Crstal Structure in the Bi(Pb)-Sr-Ca-Cu-O System[J]. Acta Physico-Chimica Sinica, ;1990, 6(05): 519-522. doi: 10.3866/PKU.WHXB19900503 shu

Effects of High Valence Cations Doped on the Phase Formation and the Crstal Structure in the Bi(Pb)-Sr-Ca-Cu-O System

1.
Department of Chemistry, Peking University, Beijing; Department of Physics, Peking University, Beijing; Department of Chemistry, Guangxi University

Received Date: 3 May 1990
Available Online: 15 October 1990

The effects of high valence cations M~(n+) (n≥4) doped on the phase formation and the structure stability have been investigated. In the crystal structure X_2Sr_2Ca_2Cu_3O_(10)(X = Bi_(1-x-y)Pb_xM_y), the high valence cations M~(n+), Bi~(3+), and Pb~(2+) were deter-mined to statistically distribute at the bismuth positions. The bismuth valence is raised and the positions of oxygen atoms in the (XO_2X) double layers are fully occupied. Conseqently, The structural stability is increased. The phase 2223 was found to form more rapidly by doping and the single phase with T_c(0)>110 K can be obtained more easily.
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