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Citation: Wang Zhiyu, He Guozhong, Lou Nanquan. CHEMILUMINESCENT POLARIZATION STUDIES OF Ba(¹S) +N₂O REACTION[J]. Acta Physico-Chimica Sinica, ;1988, 4(06): 653-656. doi: 10.3866/PKU.WHXB19880617 shu

CHEMILUMINESCENT POLARIZATION STUDIES OF Ba(¹S) +N₂O REACTION

1.
Dalian Institute of Chemical Physics; CAS

Received Date: 20 April 1987
Available Online: 15 December 1988

The variation of ehemiluminescent polarization for reaction Ba(~1S)+N_2O with respect to the Ba beam temperature or the average collision energy E_(rtr) was studied under the single collision condition on beam-gas apparatus. If E_(rtr)<0.06 eV, the distribution of rotational angular momentum for product BaO, i.e. -<P_2(J′·V_r)>, increased with the impact energy; while E_(rtr)>0.06 eV, -<P_2(J′·V_r)> decreased with the E_(rtr). It is plausible to point out the corresponding relationship between the characteristics of the reaction potential surface and the conformation of the intermediate complexes.
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CHEMILUMINESCENT POLARIZATION STUDIES OF Ba(1S) +N2O REACTION

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CHEMILUMINESCENT POLARIZATION STUDIES OF Ba(¹S) +N₂O REACTION