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Citation: Liu Juzheng*, Feng Yan, Jiang Shimei, Zhao Wenyun, Liang Yinqiu. THE VIBRATIONAL SPECTRA OF ORGANOMETALLIC COMPOUNDS (Ⅱ) FT-INFRARED, LASER RAMAN SPECTRA AND NORMAL COORDINATE CALCULATION FOR 1,1'-DIMETHYLFERROCENE[J]. Acta Physico-Chimica Sinica, ;1988, 4(06): 578-586. doi: 10.3866/PKU.WHXB19880604 shu

THE VIBRATIONAL SPECTRA OF ORGANOMETALLIC COMPOUNDS (Ⅱ) FT-INFRARED, LASER RAMAN SPECTRA AND NORMAL COORDINATE CALCULATION FOR 1,1'-DIMETHYLFERROCENE

1.
Institute of Theoretical Chemistry; Jilin University; Chang Chun

Received Date: 28 March 1987
Available Online: 15 December 1988

FT-IR and Laser Raman spectra of (CH_3Cp)_2Fe have been measured. On the basis of qualitative assignment the force constants of Cp_2M(M=Mn,Fe,Ru) obtained by G-F matrix have been translated to the molecule of (CH_3Cp)_2Fe, only the metal coordinate force constants have been adjusted. The same method of G-F matrix has been used for calculating the vibrational spectra frequencies of (CH_3Cp)_2Fe, the result is consistent with the observal one.
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