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Citation: Liu Xianyou, Zhou Lixing*, Yin Anxue, Zheng Lubin. ADSORPTION CALORIMETRIC STUDY FOR CYCLOHEXENE AND 2-METHYL-PENTENE-1 ON SEVERAL Y-ZEOLITES[J]. Acta Physico-Chimica Sinica, ;1988, 4(05): 489-493. doi: 10.3866/PKU.WHXB19880510 shu

ADSORPTION CALORIMETRIC STUDY FOR CYCLOHEXENE AND 2-METHYL-PENTENE-1 ON SEVERAL Y-ZEOLITES

1.
Dalian Institute of Chemical Physics; Chinese Academy of Sciences

Received Date: 14 February 1987
Available Online: 15 October 1988

By using SETARAM heat-flow calorimeter the differential heats of adsorption for cyclohexene and 2-methyl-pentene-1 on NaY, CaY, R_EY and HY zeolites at ambient temperature have been measured. By means of Benson's method for the estimation of thermochemical data, the heats of adsorption for tertiary and secondary carbonium ions have been obtained. According to the differnce between heats of adsorption for cyclohexene and 2-methyl-pentene-1 at the same adsorption amounts the adsorption mechanism for cyclohexene and 2-methyl-pentene-1 on the zeolites has been discussed.
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