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Citation: You Xiaozeng, Meng Qingjin, Yang Xinshui, Sun Shouheng, Bu Xiuren,
Huang Jinshun. SYNTHESIS AND STRUCTURE OF DINUCLEAR COBALT CLUSTER (C₆H₅CO₂CH₂C)₂Co₂(CO)₆[J]. Acta Physico-Chimica Sinica, ;1988, 4(04): 428-431. doi: 10.3866/PKU.WHXB19880421 shu

SYNTHESIS AND STRUCTURE OF DINUCLEAR COBALT CLUSTER (C₆H₅CO₂CH₂C)₂Co₂(CO)₆

1.
Coordination Chemistry Institute; Nanjing University
Fujian Institute of Research on the Structure of Matter; Academia Sinica

Received Date: 7 January 1987
Available Online: 15 August 1988

The cluster (C_6H_5CO_2CH_2C)_2Co_2(CO)_6 has been synthesized and characterized by element analysis, IR, ~1H NMR etc. Its crystal structure has been determined by X-ray diffraction analysis with R=0.060. The crystal is triclinic, space group P_1 with a=0.8933(3) nm, b=1.1830(6) nm, c=1.3199(3) nm, α=65.64(3)°, β=84.55(3)°, γ=72.03(4)°, z=2, D_x=1.584 g cm~(-1) The C≡C and Co-Co form a tetrahedron with appoximate C_(2V) symmetry. The Co-Co bond is metl singal bond. The hybrid state of carbon atoms in the acetylene is between sp and sp~2.
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SYNTHESIS AND STRUCTURE OF DINUCLEAR COBALT CLUSTER (C6H5CO2CH2C)2Co2(CO)6

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SYNTHESIS AND STRUCTURE OF DINUCLEAR COBALT CLUSTER (C₆H₅CO₂CH₂C)₂Co₂(CO)₆