Citation: Liu Renzhang, Wang Shouzhi. THE CHEMILUMINESCENT STUDIES OF THE REACTIONS OF Pb WITH DISCHARGED OXYGEN, O2(1△)[J]. Acta Physico-Chimica Sinica, ;1987, 3(06): 592-598. doi: 10.3866/PKU.WHXB19870607
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The chemiluminescent spectra of the reactions of Pb with discharged oxygen, O_2(1Δ), have deen measured in an atomic beam apparatus, and some new bands have been obtained, When the presure of the observed region was larger than 2.5× 10~(-2) Torr, the intensities of the(3,0) and (4,0) viberational bands of the B~3Π-X~1Σ~+ transition were enhanced remarkedly, this can be interpreted with the aid of the processes of the near-resonance collision transfer energy between PbO and O_2 (1Δ) as well as the collision induced in tramolecular energy transfer of PdO.
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