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Citation:
Sun Yukun. CONNECTION AND COMPARISON OF DIFFERENT FORMULAS OF HOMOLO US RULE OF ORGANIC COMPOUNDS[J]. Acta Physico-Chimica Sinica,
;1987, 3(05): 539-543.
doi:
10.3866/PKU.WHXB19870518
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In this paper, the author deduced the Gradation Rule of the Conjugated Homo- logs E=a+b/N from the Linear Rule of the Homolo us Energy Factor E=a+b((2k-1)/k)sin(kπ/(2N+1)) and acquired a new Homolo us Function E=a+b(2k-1)/(N+1/2), which is better than Gradation Rule of the Conjugated Homologs. Five formulas of Linear Rule resently reported were tested and compared by using 96 series of data of photo-electron spectroscopy and 159 series of data of electren spectroscopy. The author holds that the Linear Rule of the Homol us Energy Factor is better.
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