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Citation: Wang Dianxun, Li Ercheng, Xu Guangzhi. A STUDY OF XPS SHAKE-UP SATELLITE AND VALENCE BAND PEAKS ON (Ph₃P)₃Cu_nX_n COMPLEXES[J]. Acta Physico-Chimica Sinica, ;1987, 3(01): 85-87. doi: 10.3866/PKU.WHXB19870115 shu

A STUDY OF XPS SHAKE-UP SATELLITE AND VALENCE BAND PEAKS ON (Ph₃P)₃Cu_nX_n COMPLEXES

1.
Institute of Chemistry; Academia Sinica; Beijing

Received Date: 23 July 1985
Available Online: 15 February 1987

In this paper XPS studies of (Ph_3P)_3Cu_nX_n complexes have been reported. The XPS shifts of inner shell binding energies show that P→Cu dative bond exists in (Ph_3P)_3Cu_nX_n complexes. The large shifts of Cu 2P_(3/2) and P 2d binding energies of (Ph_3P)_3Cu(CN) and (Ph_3P)_3Cu_2(CN)_2 complexes are due to the feedback effect of Cu 3d~(10) electrons. The results XPS shake-up satellite peaks furthermore confirm the existence of P→Cu dative bond in these complexes. In addition, XPS valence band spectra of these complexes appear to be superposition from the XPS valence band spectra of CuX and Ph_3P.
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A STUDY OF XPS SHAKE-UP SATELLITE AND VALENCE BAND PEAKS ON (Ph3P)3CunXn COMPLEXES

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通讯作者: 陈斌, bchen63@163.com

A STUDY OF XPS SHAKE-UP SATELLITE AND VALENCE BAND PEAKS ON (Ph₃P)₃Cu_nX_n COMPLEXES