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Citation: Mu Guorong, Ren Lianwei, Li Changlin. KINETICS OF UNIMOLECULAR REACTION OF CF₂HCl ON W SURFACE[J]. Acta Physico-Chimica Sinica, ;1986, 2(03): 284-287. doi: 10.3866/PKU.WHXB19860315 shu

KINETICS OF UNIMOLECULAR REACTION OF CF₂HCl ON W SURFACE

1.
Second Department of Physics, Fudan University, Shanghai

Received Date: 11 April 1985
Available Online: 15 June 1986

The unimolecular reaction of CF_2HCl on W filament has been studied. This reaction shows zero order at rather high pressure. The temperature threshold is about 440 ℃. The apparent activation energy of this reaction is 119.7 kJ mol~(-1) which is about a half of the activation energy for homogeneous unimolecular reaction of CF_2HCl, 233.5 kJ mol~(-1).
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KINETICS OF UNIMOLECULAR REACTION OF CF2HCl ON W SURFACE

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KINETICS OF UNIMOLECULAR REACTION OF CF₂HCl ON W SURFACE