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Citation: Guo Guolin, Xie Youchang, Tang Youqi. EFFECT OF TITANIAM ETHER COMPLEX ON THE SURFACE STRUCTURE OF THE 3TiCI₃·AICI₃ CATALYST[J]. Acta Physico-Chimica Sinica, ;1985, 1(01): 57-65. doi: 10.3866/PKU.WHXB19850108 shu

EFFECT OF TITANIAM ETHER COMPLEX ON THE SURFACE STRUCTURE OF THE 3TiCI₃·AICI₃ CATALYST

1.
Laboratory for Structre of Matter; Institute of Physical Chemistry; Peking University

Received Date: 10 August 1984
Available Online: 15 February 1985

It has been Verified by XPS, IR, NMR and solvent washing that TiCl_4·2Et_2O complex is able to react with 3TiCl_3·AlCl_3 catalyst in solid phase as show in table (1—1), table (3—2) and Fig (2—1) — (2—4). The solid-solid reaction is as follows
TiCl_4·2Et_2O+2AlCl_3—→2AlCl_3·Et_2O+TiCl_4
After treatment with TiCl_4·2Et_2O complex the surface structure of the catalyst could be described approximately by a three layer model.
Properties of the catalyst are effected by the donor and acceptor components from whi...
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EFFECT OF TITANIAM ETHER COMPLEX ON THE SURFACE STRUCTURE OF THE 3TiCI3·AICI3 CATALYST

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EFFECT OF TITANIAM ETHER COMPLEX ON THE SURFACE STRUCTURE OF THE 3TiCI₃·AICI₃ CATALYST