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Citation: Jinyi Sun, Lin Ma, Yanjie Xi, Jing Wang. Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment[J]. University Chemistry, ;2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094 shu

Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment

School of Chemistry and Chemical Engineering, Lingnan Normal University, Zhanjiang 524048, Guangdong Province, China

Corresponding author: Lin Ma, mal@lingnan.edu.cn
Received Date: 25 October 2023
Revised Date: 13 December 2023

This comprehensive chemistry experiment utilizes vanadium trichloride and hexamethylenetetramine as precursors to synthesize a heterostructured composite material consisting of nano-scaled vanadium nitride particles embedded in nitrogen-doped carbon sheets through template-assisted heat treatment and nitridation methods. Furthermore, the electrocatalytic nitrogen reduction performance of the composite material is thoroughly examined. The experimental procedure encompasses interdisciplinary knowledge and practical skills in inorganic chemistry, physical chemistry, and analytical chemistry, with a focus on cutting-edge scientific research. By stimulating students’ interest in learning and enhancing their application abilities, this experiment aims to cultivate students’ disciplinary literacy, research innovation capabilities, and sense of social responsibility.
- Vanadium nitride,
- Nitrogen-doped carbon,
- Electrocatalysis,
- Comprehensive chemical experiment
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
  Abghoui, Y.; Garden, A. L.; Hlynsson, V. F.; Björgvinsdóttir, S.; Ólafsdóttir, H.; Skúlason, E. Phys. Chem. Chem. Phys. 2015, 17(7), 4916
7. [7]
  Wei, P.; Geng, Q.; Channa, A. I.; Tong, X.; Luo, Y.; Lu, S.; Chen, G.; Gao, S.; Wang, Z.; Sun, X. Nano Res. 2020, 13, 2968.<
1. [1]
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