Citation: Xiaohan Wang, Dongxiao Cao, Wei Li, Yan Chen, Anna Tang, Deming Kong. Synthesis and Application of Morphology Controllable Covalent Organic Frameworks[J]. University Chemistry, ;2023, 38(5): 110-118. doi: 10.3866/PKU.DXHX202206098 shu

Synthesis and Application of Morphology Controllable Covalent Organic Frameworks

Tianjin Key Laboratory of Biosensing and Molecular Recognition, Research Center for Analytical Sciences, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Anna Tang, tanganna@nankai.edu.cn
Received Date: 29 June 2022

Covalent organic frameworks (COFs), a new type of crystalline porous materials, have attracted considerable attention in many fields such as separation, catalysis, drug release, and optoelectronics. The crystallinity and morphology of COFs determine their application. In this study, the synthetic methods and applications of COFs with different morphologies (spherical, thin film, rod, tubular, fibrous, belt, cage, and roll) are reviewed. Existing problems are also discussed and their potential solutions are proposed.
- Morphology controllable,
- Covalent organic frameworks,
- Synthesis,
- Application
1. [1]
  Cote, A. P.; Benin, A. I.; Ockwig, N. W.; O'Keeffe, M.; Matzger, A. J.; Yaghi, O. M. Science 2005, 310, 1166.
2. [2]
  Ma, W. D.; Zheng, Q.; He, Y. T.; Li, G. R.; Guo, W. J.; Lin, Z.; Zhang, L. J. Am. Chem. Soc. 2019, 141, 18271.
3. [3]
  Li, Y. X.; Zhang, H. N.; Chen, Y. T.; Huang, L.; Lin, Z.; Cai, Z. W. ACS Appl. Mater. Interfaces 2019, 11, 22492.
4. [4]
  Liang, H.; Xu, H. B.; Zhao, Y. T.; Zheng, J.; Zhao, H.; Li, G. L.; Li, C. P. Biosens. Bioelectron. 2019, 144, 111691.
5. [5]
  Li, W.; Wang, R.; Jiang, H. X.; Chen, Y.; Tang, A. N.; Kong, D. M. Talanta 2022, 236, 122829.
6. [6]
  Wang, K.; Wang, W.; Pan, S.; Fu, Y.; Dong, B.; Wang, H. Appl. Mater. Today 2020, 19, 100550.
7. [7]
  Li, M. M.; Qiao, S.; Zheng, Y. L.; Andaloussi, Y. H.; Li, X.; Zhang, Z. J.; Li, A.; Cheng, P.; Ma, S. Q.; Chen, Y. J. Am. Chem. Soc. 2020, 142, 6675.
8. [8]
  Yin, Z. J.; Xu, S. Q.; Zhan, T. G.; Qi, Q. Y.; Wu, Z. Q.; Zhao, X. Chem. Commun. 2017, 53, 7266.
9. [9]
  Li, W.; Jiang, H. X.; Cui, M. F.; Wang, R.; Tang, A. N.; Kong, D. M. J. Hazard. Mater. 2022, 432, 128705.
10. [10]
  Kandambeth, S.; Venkatesh, V.; Shinde1, D. B.; Kumari, S.; Halder, A.; Verma, S.; Banerjee, R. Nat. Commun. 2015, 6, 6786.
11. [11]
  Sasmal, H. S.; Halder, A.; Kunjattu, S.; Dey, K.; Nadol, A.; Ajithkumar, T. G.; Bedadur, P. R.; Banerjee, R. J. Am. Chem. Soc. 2019, 141, 20371.
12. [12]
  Shinde, D. B.; Cao, L.; Wonanke, A. D. D.; Li, X.; Kumar, S.; Liu, X. W.; Hedhili, M. N.; Emwas, A. H.; Addicoat, M.; Huang, K. W.; et al. Chem. Sci. 2020, 11, 5434.
13. [13]
  Wang, X. H.; Li, W.; Jiang, H. X.; Chen, Y.; Gao, R. Z.; Tang, A. N.; Kong, D. M. Microchim. Acta 2021, 188, 235.
14. [14]
  Hao, Q.; Li, Z. J.; Lu, C.; Sun, B.; Zhong, Y. W.; Wan, L. J.; Wang, D. J. Am. Chem. Soc. 2019, 141, 19831.
15. [15]
  Chen, D. D.; Huang, S.; Zhong, L.; Wang, S. J.; Xiao, M.; Han, D. M.; Meng, Y. Z. Adv. Funct. Mater. 2020, 30, 1907717.
16. [16]
  Pachfule, P.; Kandmabeth, S.; Mallick, A.; Banerjee, R. Chem. Commun. 2015, 51, 11717.
17. [17]
  Gole, B.; Stepanenko, V.; Rager, S.; Grune, M.; Medina, D. D.; Bein, T.; Wurthner, F.; Beuerle, F. Angew. Chem. Int. Ed. 2018, 57, 846.
18. [18]
  Rodriguez-San-Miguel, D.; Abrishamkar, A.; Navarro, J. A. R.; Rodriguez-Trujillo, R.; Amabilino, D. B.; Mas-Ballesté, R.; Zamora, F.; Puigmartí-Luis, J. Chem. Commun. 2016, 52, 9212.
19. [19]
  Huang, W.; Jiang, Y.; Li, X.; Li, X.; Wang, J.; Wu, Q.; Liu, X. ACS Appl. Mater. Interfaces 2013, 5, 8845.
20. [20]
  Wan, S.; Guo, J.; Kim, J.; Ihee, H.; Jiang, D. L. Angew. Chem. Int. Ed. 2008, 47, 8826.
21. [21]
  Zhang, F. Y.; Zhang, J. L.; Zhang, B. X.; Tan, X. N.; Shao, D.; Shi, J. B.; Tan, D. X.; Liu, L. F.; Feng, J. Q.; Han, B. X.; et al. ChemSusChem 2018, 11, 3576.
22. [22]
  Jennings, J.; Beija, M.; Richez, A. P.; Cooper, S. D.; Mignot, P. E.; Thurecht, K. J.; Jack, K. S.; Howdle, S. M. J. Am. Chem. Soc. 2012, 134, 4772.
23. [23]
  Li, H. Y.; Bredas, J. L. Chem. Mater. 2019, 31, 3265.
24. [24]
  Florian, B.; Bappaditya, G. Angew. Chem. Int. Ed. 2018, 57, 4850.
25. [25]
  Ma, J. X.; Li, J.; Chen, Y. F.; Ning, R.; Ao, Y. F.; Liu, J. M.; Sun, J. L.; Wang, D. X.; Wang, Q. Q. J. Am. Chem. Soc. 2019, 141, 3843.
26. [26]
  Unterlass, M. M. Angew. Chem. Int. Ed. 2018, 57, 2292.
27. [27]
  Chen, Y.; Li, W.; Wang, X. H.; Gao, R. Z.; Tang, A. N.; Kong, D. M. Mater. Chem. Front. 2021, 5, 1253.
1. [1]
  Ying Chen , Ronghua Yan , Weiyan Yin . Research Progress on the Synthesis of Metal Single-Atom Catalysts and Their Applications in Electrocatalytic Hydrogen Evolution Reactions. University Chemistry, 2025, 40(9): 344-353. doi: 10.12461/PKU.DXHX202503066
2. [2]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
3. [3]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
4. [4]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
5. [5]
  Lin′an CAO , Dengyue MA , Gang XU . Research advances in electrically conductive metal-organic frameworks-based electrochemical sensors. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 1953-1972. doi: 10.11862/CJIC.20250160
6. [6]
  Cheng-an Tao , Jian Huang , Yujiao Li . Exploring the Application of Artificial Intelligence in University Chemistry Laboratory Instruction. University Chemistry, 2025, 40(9): 5-10. doi: 10.12461/PKU.DXHX202408132
7. [7]
  Lixing ZHANG , Yaowen WANG , Xu HAN , Junhong ZHOU , Jinghui WANG , Liping LI , Guangshe LI . Research progress in the synthesis of fluorine-containing perovskites and their derivatives. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1689-1701. doi: 10.11862/CJIC.20250007
8. [8]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
9. [9]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
10. [10]
  Bin SUN , Heyan JIANG . Glucose-modified bis-Schiff bases: Synthesis and bio-activities in Alzheimer′s disease therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1338-1350. doi: 10.11862/CJIC.20240428
11. [11]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
12. [12]
  Tiantian Zheng , Huiyi Wang , Huimin Li , Xuanhe Liu , Hong Shang . Anti-Counterfeiting National Salvation Chronicle of 006. University Chemistry, 2024, 39(9): 254-258. doi: 10.3866/PKU.DXHX202307032
13. [13]
  Wenli FENG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress on ultralong room temperature phosphorescent carbon dots. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 833-846. doi: 10.11862/CJIC.20240308
14. [14]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
15. [15]
  Yu Liu , Pengfei Li , Yize Liu , Zaicheng Sun . Recent advances in carbon dots as a single photocatalyst. Acta Physico-Chimica Sinica, 2026, 42(2): 100167-0. doi: 10.1016/j.actphy.2025.100167
16. [16]
  Xinyi Zhang , Kai Ren , Yanning Liu , Zhenyi Gu , Zhixiong Huang , Shuohang Zheng , Xiaotong Wang , Jinzhi Guo , Igor V. Zatovsky , Junming Cao , Xinglong Wu . Progress on Entropy Production Engineering for Electrochemical Catalysis. Acta Physico-Chimica Sinica, 2024, 40(7): 2307057-0. doi: 10.3866/PKU.WHXB202307057
17. [17]
  Lei Feng , Ze-Min Zhu , Ying Yang , Zongbin He , Jiafeng Zou , Man-Bo Li , Yan Zhao , Zhikun Wu . Long-Pursued Structure of Au₂₃(S-Adm)₁₆ and the Unexpected Doping Effects. Acta Physico-Chimica Sinica, 2024, 40(5): 2305029-0. doi: 10.3866/PKU.WHXB202305029
18. [18]
  Chunling Qin , Shuang Chen , Hassanien Gomaa , Mohamed A. Shenashen , Sherif A. El-Safty , Qian Liu , Cuihua An , Xijun Liu , Qibo Deng , Ning Hu . Regulating HER and OER Performances of 2D Materials by the External Physical Fields. Acta Physico-Chimica Sinica, 2024, 40(9): 2307059-0. doi: 10.3866/PKU.WHXB202307059
19. [19]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
20. [20]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015

Get Citation

PDF

XML

Metrics

PDF Downloads(17)
Abstract views(1760)
HTML views(150)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142