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Citation: YANG Zhanqiang, LI Zongying, YANG Dehui, ZHANG Feifang, YANG Bingcheng. A polymer resin surface polymerization-based hydroxide-selective anion exchange stationary phase[J]. Chinese Journal of Chromatography, ;2020, 38(4): 452-457. doi: 10.3724/SP.J.1123.2019.07031 shu

A polymer resin surface polymerization-based hydroxide-selective anion exchange stationary phase

1.
School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China;
2.
Minghao Chromatographic Technology Corp., Suzhou 215513, China

Corresponding author: YANG Bingcheng, bcyang@ecust.edu.cn
Received Date: 28 July 2019

Fund Project: National Key Research and Development Program of China (No. 2018YFC1603500).

A polystyrene-divinylbenzene (PS-DVB) microspheres-based hydroxide-selective anion exchange stationary phase is described. This stationary phase is obtained by the surface polymerization of an allyl glycidyl ether (AGE) and the pendant vinyl groups onto the surface of PS-DVB, followed by open-ring of the epoxy groups using an alkylol amine (abbreviated as P@A-M). Both alkylol amines were compared in terms of separation performance of the stationary phase. Scanning electron microscopy, infrared spectroscopy, and elemental analyses were carried out to characterize the stationary phase. The results indicated that the quaternary amine group was successfully introduced onto the surface of the PS-DVB microspheres, and that there was no obvious change in the physicochemical properties of the resin during the surface polymerization reaction. The P@A-M phase showed high hydroxide-selectivity and good separation performance (resolution>1.5) as well as high running stability (relative standard deviation of retention times<1.13%). The utility of the P@A-M phase was demonstrated by using it for the determination of inorganic anions in the tea.
- ion chromatography (IC),
- stationary phase,
- pendant vinyl group,
- surface polymerization,
- allyl glycidyl ether
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1.
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