Citation: PENG Sheng, LI Huan, SHI Shuyun. Preparation of hydrophilic, magnetic molecularly imprinted resins of chlorogenic acid and evaluation of its solid-phase extraction performance[J]. Chinese Journal of Chromatography, ;2019, 37(3): 293-298. doi: 10.3724/SP.J.1123.2018.11026 shu

Preparation of hydrophilic, magnetic molecularly imprinted resins of chlorogenic acid and evaluation of its solid-phase extraction performance

PENG Sheng ^1,2, ,
LI Huan ³ ,
SHI Shuyun ^1,2,3

1.
Key Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie 427000, China;
2.
National & Local United Engineering Laboratory of Integrative Utilization Technology of Eucommiaulmoides, Jishou University, Jishou 416000, China;
3.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China

Received Date: 18 November 2018

Fund Project: National Natural Science Foundation of China (No. 81673585)

Hydrophilic, magnetic molecularly imprinted resins (MMIRs) were fabricated inside Fe₃O₄@mSiO₂ pores by the one-pot copolycondensation of chlorogenic acid (CGA), resorcinol, melamine, and formaldehyde. The final porous MMIRs with larger numbers of surface recognition sites were obtained by removing mSiO₂. The successful preparation of MMIRs was confirmed using transmission electron microscopy, Fourier transform infrared spectroscopy, vibrating sample magnetometry, thermo-gravimetric analysis, and water contact angle analysis. The analyses suggest that the MMIRs have excellent hydrophilicity and magnetic solid-phase extraction efficiency. The MMIRs had a good adsorption capacity (50.87 mg/g), fast rate of adsorption (equilibrium was attained at 70 min), and specific recognition for CGA. The MMIRs, in combination with high performance liquid chromatography, were directly used for the selective extraction and determination of CGA in Duzhong brick tea. The limit of detection and recovery were 0.7 mg/L and 93.1%-109.4%, respectively, with relative standard deviations of less than 9.6%. The proposed strategy was extremely promising for the facile, rapid, and selective determination of CGA in real aqueous samples.
- hydrophilic molecularly imprinted resin,
- solid phase extraction (SPE),
- high performance liquid chromatography (HPLC),
- chlorogenic acid,
- complex sample
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
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