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Citation: LI Haijing, LIU Guozhu, ZHANG Xiangwen. Analysis of kerosene-based endothermic hydrocarbon fuel using comprehensive two-dimensional gas chromatography coupled to mass spectrometry[J]. Chinese Journal of Chromatography, ;2018, 36(8): 780-785. doi: 10.3724/SP.J.1123.2018.02030 shu

Analysis of kerosene-based endothermic hydrocarbon fuel using comprehensive two-dimensional gas chromatography coupled to mass spectrometry

Key Laboratory of Green Chemical Technology of Ministry of Education, Tianjin University, Tianjin 300072, China

Received Date: 27 February 2018

Fund Project: National Natural Science Foundation of China (No.21522605).

Hydrocarbon fuels are mainly composed of n-alkenes, iso-alkanes, cycloalkanes (primarily single-and double-ring), alkylbenzenes, indans, tetralins, naphthalene, and alkylnaphthalenes. Different hydrocarbon classes impart different properties to a fuel. An identification method of hydrocarbon classes in kerosene-based endothermic hydrocarbon fuel was established using comprehensive two-dimensional gas chromatography coupled to mass spectrometry (GC×GC-MS). Moreover, the corresponding quantitative determination was achieved using the effective carbon number correction factors of GC×GC-FID. The effects of the main chromatographic conditions such as the column system, program heating conditions, and modulation period on the separation of fuels were discussed. Nine hydrocarbon fuels were analyzed. The results showed that the contents of paraffin and cycloalkanes are consistent with the results obtained using the standard test method ASTM D2425. The relative error is within ±10%. The carbon content calculated using this method has an error of less than 0.5% compared with the elemental analysis method. This method does not require complicated pretreatment, and the sample can be injected directly after dilution. Compared with the traditional GC-MS, the operation is simple, and the differences among various samples can be observed intuitively, which helps in improving the performance of the fuel.
- comprehensive two-dimensional gas chromatography (GC×GC),
- hydrocarbon class,
- hydrocarbon fuel
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Analysis of kerosene-based endothermic hydrocarbon fuel using comprehensive two-dimensional gas chromatography coupled to mass spectrometry

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com