Citation: LI Wulin, LI Xuemin, LI Genrong, LI Yanfei, XU Yi, LI Zequan. Determination of 15 phthalate esters in plastic products by ultra performance convergence chromatography[J]. Chinese Journal of Chromatography, ;2016, 34(8): 795-800. doi: 10.3724/SP.J.1123.2016.03017 shu

Determination of 15 phthalate esters in plastic products by ultra performance convergence chromatography

LI Wulin ^1,2,, ,
LI Xuemin ² ,
LI Genrong ¹ ,
LI Yanfei ¹ ,
XU Yi ² ,
LI Zequan ²

1.
1. Chongqing Academy of Metrology and Quality Inspection, Chongqing 401123, China;
2.
2. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, China

Corresponding author: LI Wulin,
Received Date: 14 March 2016

Fund Project:

Ultra performance convergence chromatography (UPC²) is cost effective, sustainable, and it uses green technology that lowers the use of organic solvents. Based on these advantages, a method was developed for the determination of 15 phthalate esters in plastic products by UPC². The samples were extracted with hexane and then quantitatively analyzed by UPC². The separation of the 15 phthalate esters was achieved on an ACQUITY UPC² HSS C18 SB column (150 mm×3 mm, 1.8 μ m) by a gradient elution with supercritical CO₂ and acetonitrile as mobile phases. External standard method was used for the quantitative determination and the calibration curves showed good linearity in the concentration range of 0.5-10 mg/L for the phthalate esters with correlation coefficients higher than 0.9960. The limits of quantification of the phthalate esters were 1.0-2.2 mg/kg. Their spiked recoveries were 78.1%-122.3%, and the relative standard deviation range was from 2.95% to 8.26%. The method can be successfully applied for the determination of the phthalate esters in plastic products.
- ultra performance convergence chromatography (UPC²),
- photodiode array detector (PDA),
- phthalate esters (PAEs),
- plastic
1. [1]
  [1] Makkliang F, Kanatharana P, Thavarungkul P, et al. Food Chem, 2015, 166: 275
2. [2]
  [2] Wang H F, Dong X H, Jia B, et al. Chinese Journal of Chromatography, 2015, 33(5): 545 王会锋, 董小海, 贾斌, 等. 色谱, 2015, 33(5): 545
3. [3]
  [3] Viñas P, Campillo N, Pastor-Belda M, et al. J Chromatogr A, 2015, 1376: 18
4. [4]
  [4] Wu P G, Cai C G, Yang D J, et al. J Sep Sci, 2015, 38(2): 254
5. [5]
  [5] Hadjmohammadi M R, Ranjbari E. Int J Environ An Ch, 2012, 92(11): 1312
6. [6]
  [6] Chen B, Zhang L P. Polym Test, 2013, 32(4): 681
7. [7]
  [7] Gao H, Xu Y Y, Sun L, et al. Chinese Journal of Chromatography, 2015, 33(6): 622 高慧, 许媛媛, 孙丽, 等. 色谱, 2015, 33(6): 622
8. [8]
  [8] Xu D M, Deng X J, Fang E H, et al. J Chromatogr A, 2014, 1324: 49
9. [9]
  [9] Wang Y L, Shi X Y, Wu Z S, et al. Chinese Journal of Experimental Traditional Medical Formulae, 2013, 19(5): 86 王运丽, 史新元, 吴志生, 等. 中国实验方剂学杂志, 2013, 19(5): 86
10. [10]
  [10] Casas-Hernández A M, Aguilar-Caballos M P, Gómez-Hens A. Anal Lett, 2003, 36(5): 1017
11. [11]
  [11] Zhou Q, Gao B Y, Zhang X, et al. Food Chem, 2014, 143: 199
12. [12]
  [12] Lin C H, Xie X Q, Fan N L, et al. Chinese Journal of Chromatography, 2015, 33(4): 397 林春花, 谢贤清, 范乃立, 等. 色谱, 2015, 33(4): 397
13. [13]
  [13] Gong X, Qi N L, Wang X X, et al. Food Chem, 2014, 162: 172
14. [14]
  [14] Tang J, Ding Y C, Cao X Z, et al. Chinese Journal of Chromatography, 2014, 32(11): 1230 汤娟, 丁友超, 曹锡忠, 等. 色谱, 2014, 32(11): 1230
15. [15]
  [15] Zhang Y, Xiao Z Y, Lv S R, et al. J Sep Sci, 2016, 39(5): 993
16. [16]
  [16] Ni X J, Xing X P, Cao Y H, et al. Food Chem, 2016, 190: 386
17. [17]
  [17] Lin C H, Rui P X, Lei Z W, et al. Chinese Journal of Applied Chemistry, 2016, 33(2): 238 林春花, 芮培欣, 雷志伟, 等. 应用化学, 2016, 33(2): 238
18. [18]
  [18] Dai X W, Wei B W, Wang X L, et al. Chinese Journal of Chromatography, 2015, 33(10): 1059 戴雪伟, 卫碧文, 望秀丽, 等. 色谱, 2015, 33(10): 1059
19. [19]
  [19] Xi H M, Sun M H. Pollution Control Technology, 2006, 19(6): 49 奚海明, 孙梅华. 污染防治技术, 2006, 19(6): 49
20. [20]
  [20] GB/T 21928-2008
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