Citation: Tomoyuki IKAI, Takayuki YAMADA. Synthesis of novel glucose-based polymers and their applications as chiral stationary phases for high performance liquid chromatography[J]. Chinese Journal of Chromatography, ;2016, 34(1): 4-9. doi: 10.3724/SP.J.1123.2015.10037 shu

Synthesis of novel glucose-based polymers and their applications as chiral stationary phases for high performance liquid chromatography

Tomoyuki IKAI ^, ,
Takayuki YAMADA

1.
Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

Corresponding author: Tomoyuki IKAI,
Received Date: 26 October 2015

Fund Project: This work was supported by the Japan Society for the Promotion of Science (JSPS) KAKENHI Grants-in-Aid for Scientific Research (C) (Grant No. 26410129). (JSPS) KAKENHI Grants-in-Aid for Scientific Research (C) (Grant No. 26410129)

Two novel polymers containing glucose units as the main-chain that only differ in terms of their regioregularity were synthesized to evaluate their chiral recognition abilities as chiral stationary phases (CSPs) for high performance liquid chromatography (HPLC). The regioregular polymer (poly-5) shows clear resolution ability for the racemate of cobalt (Ⅲ) acetylacetonate (Co(acac)₃), whereas the corresponding regioirregular polymer (poly-3) does not show any chiral recognition for Co(acac)₃. The regioregular polymer main-chain seems to play an important role not only in providing an efficient interaction with the racemate but also in expressing the chiral recognition ability as a CSP for HPLC.
- biomass,
- chiral discrimination,
- chirality,
- enantioseparation,
- glucose,
- regioregularity
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沈阳化工大学材料科学与工程学院沈阳 110142