Citation: CHENG Jianguo, LIU Kaiying, BAI Mindong, CHENG Chao, YU Yixuan, ZHOU Xinying. Determination of 2-methylisoborneol and geosmin in drinking water using headspace solid phase micro-extraction coupled with gas chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, ;2015, 33(12): 1287-1293. doi: 10.3724/SP.J.1123.2015.08031 shu

Determination of 2-methylisoborneol and geosmin in drinking water using headspace solid phase micro-extraction coupled with gas chromatography-mass spectrometry

CHENG Jianguo ¹ ,
LIU Kaiying ^1,, ,
BAI Mindong ^1,2,, ,
CHENG Chao ¹ ,
YU Yixuan ¹ ,
ZHOU Xinying ¹

1.
1. Dalian Maritime University, Dalian 116026, China;

Corresponding author: LIU Kaiying, BAI Mindong,
Received Date: 26 August 2015

Fund Project: 国家科技支撑计划项目(2013BAC06B00) (2013BAC06B00)国家高技术研究发展计划("863"计划)项目(2012AA062609) ("863"计划)项目(2012AA062609)辽宁省重点实验室基础研究项目(LZ2015008) (LZ2015008)中央高校基本科研业务费专项资金(3132015140). (3132015140)

The odorous compounds of 2-methylisoborneol (2-MIB) and geosmin (GSM) heavily produced and released in water source are one of the most important factors leading to off-flavor emergencies and resident water consumption panic in drinking water. A headspace solid phase micro-extraction (HS-SPME) combined with gas chromatography-mass spectrometry (GC-MS) method was established for the simultaneous determination of these two trace earthy and musty compounds in reservoir water, reservoir soil and tap water. The conditions of HS-SPME, such as salt amount, extraction time and extraction temperature, were optimized based on orthogonal analysis. The qualitative and quantitative analyses of 2-MIB and GSM were carried out in the electron impact (EI)-selective ion scanning mode. The results showed that the linear relationship between peak area and concentration of 2-MIB and GSM was good enough (r²≥0.998) from 5 to 1000 ng/L, the limits of detection were 0.72 ng/L for 2-MIB, 0.34 ng/L for GSM and the limits of quantification were 2.40 ng/L for 2-MIB, 1.13 ng/L for GSM. When the target samples spiked in the range of 10-600 ng/L, the average recoveries of the target compounds were 93.6%-107.7% (RSD≤6.1%, n=6). Based on the above method, the target compounds in reservoir water, reservoir soil and tap water in a certain region of Liaoning Province were analyzed. The results showed that the two target odors in reservoir water were 3.0-3.6 ng/L. As for the extract of the soil around the reservoir, 2-MIB was 8.1 ng/L and GSM was 17.8 ng/L. The odorous substances were not detected in the tap water. This method is simple, accurate, reliable, highly sensitive and no need of organic solvents. And it is suitable for the detection of 2-MIB and GSM in drinking water.
- headspace solid phase micro-extraction (HS-SPME),
- gas chromatography-mass spectrometry (GC-MS),
- 2-methylisoborneol (2-MIB),
- geosmin (GSM),
- drinking water,
- orthogonal analysis
1. [1]
  [1] Sun D L, Yu J W, An W, et al. J Environ Sci, 2013, 25(3): 460
2. [2]
  [2] Klausen C, Nicolaisen M H, Strobel B W, et al. FEMS Microbiol Ecol, 2005, 52(2): 265
3. [3]
  [3] Li Z L, Hobson P, An W, et al. Water Res, 2012, 46(16): 5165
4. [4]
  [4] Korth W, Ellis J, Bowmer K. Water Sci Technol, 1992, 25(2): 115
5. [5]
  [5] Suffet I H, Schweitzer L, Khiari D. Rev Environ Sci Bio, 2004, 3: 3
6. [6]
  [6] GB 5749-2006
7. [7]
  [7] Bartels J H M, Brady B M, Suffet I H. J AWWA, 1987, 79(1): 26
8. [8]
  [8] Shin H S, Ahn H S. Chromatographia, 2004, 59: 107
9. [9]
  [9] Li F A. Water Technology (李福安. 供水技术), 2012, 6(4): 54
10. [10]
  [10] Manickum T, John W. Hydrol Current Res, 2012, 3(3): 1000134
11. [11]
  [11] Manickum T, John W, Malungana M P. Hydrol Current Res, 2011, 2(5): 121. DOI: 10.4172/2157-7587.1000121
12. [12]
  [12] Watson S B, Brownlee B, Satchwill T, et al. Water Res, 2000, 34(10): 2818
13. [13]
  [13] Wu D Y, Duirk S E. Chemosphere, 2013, 91: 1495
14. [14]
  [14] Wu J H, Wang Z H, Wang B, et al. Chinese Journal of Chromatography (吴金浩, 王召会, 王摆, 等. 色谱), 2013, 31(12): 1218
15. [15]
  [15] Yu J W, An W, Cao N, et al. J Environ Sci, 2014, 26: 1389
16. [16]
  [16] Ma X Y, Gao N Y, Li Q S, et al. Environmental Pollution and Control (马晓雁, 高乃云, 李青松. 环境污染与防治), 2006, 28(8): 631
17. [17]
  [17] Ding Z, Peng S F, Xia W W, et al. Int J Environ Anal Chem, 2014: 697260. http://dx.doi.org/10.1155/2014/697260
18. [18]
  [18] Li L, Song L R, Gan N Q, et al. Chinese Journal of Analytical Chemistry (李林, 宋立荣, 甘南琴, 等. 分析化学), 2005, 33(8): 1058
19. [19]
  [19] Peng S F, Ding Z, Xia W W, et al. J Anal Methods Chem, 2013: 340658. http://dx.doi.org/10.1155/2013/340658
20. [20]
  [20] Wei H R, Yi X B, Tan Y, et al. Chinese Journal of Chromatography (魏海蓉, 易锡斌, 谭钺, 等. 色谱), 2015, 33(6): 577
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