Citation: YAN Lifen, LÜ Yan, SHAO Lin, ZHOU Qingdi, DONG Nan. Preparation of new solid-phase microextraction fiber based on cucurbit[7]uril coordination polymers and its application in determination of polycyclic aromatic hydrocarbons from environmental water samples[J]. Chinese Journal of Chromatography, ;2014, 32(12): 1295-1300. doi: 10.3724/SP.J.1123.2014.09015 shu

Preparation of new solid-phase microextraction fiber based on cucurbit[7]uril coordination polymers and its application in determination of polycyclic aromatic hydrocarbons from environmental water samples

YAN Lifen ¹ ,
LÜ Yan ¹ ,
SHAO Lin ¹ ,
ZHOU Qingdi ² ,
DONG Nan ^1,,

1.
1. College of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China;

Corresponding author: DONG Nan,
Received Date: 10 September 2014
Available Online: 13 October 2014
Fund Project: 国家自然科学基金项目(81160398) (81160398)教育部春晖计划项目(Z2012062). (Z2012062)

A novel solid-phase microextraction fiber was prepared via simple adhesion process. Fused-silica fiber was used as supporting substrate and the cucurbit[7]uril/Eu coordination polymers induced by [CdCl₄]^2- anion was affixed onto the surface of fused-silica fiber with high-temperature epoxy resin as a sorbent coating. The SPME coating was characterized by scanning electron microscopy and thermal analysis. Coupled to gas chromatography, the fiber was used to extract polycyclic aromatic hydrocarbons (PAHs) in aqueous samples. Analytical performances of the proposed method were investigated under the optimum extraction conditions (extraction temperature, 75 ℃; mass concentration of NaCl, 200 g/L; extraction time, 40 min; desorption time, 2 min; desorption temperature, 250 ℃) compared with commercial fibers for the same analytes. For the seven PAHs (naphthalene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene and pyrene), good linearity was obtained ranging from 1 μg/L to 1000 μg/L. Limits of detection were 0.29-2.09 μg/L with the RSDs no more than 8.6%. The established SPME-GC method was applied to determine the spiked PAHs in real river water samples and satisfactory results were obtained with recoveries between 97.2% and 109.0%. Under the optimal conditions, the extraction effect of home-made coating was similar to the commercial PDMS (polydimethylsiloxane) coating, which further confirmed its potential in the solid-phase microextraction.
- cucurbit[7]uril coordination polymers,
- solid-phase microextraction (SPME),
- gas chromatography (GC),
- polycyclic aromatic hydrocarbons,
- environmental water
1. [1]
  [1] Liu Y, Beckingham B, Ruegner H, et al. Environ Sci Technol, 2013, 47(2): 701
2. [2]
  [2] Wang R W, Liu G J, Zhang J M, et al. Energy Fuels, 2010, 24(11): 6061
3. [3]
  [3] Zhang Y, Zhang X S, Yang P, et al. Chinese Journal of Analytical Chemistry (张渝, 张新申, 杨坪, 等. 分析化学), 2011, 39(6): 799
4. [4]
  [4] Ding C M, Jin Y L, Lin S B. Chinese Journal of Analytical Chemistry (丁昌明, 金银龙, 林少彬. 分析化学), 2012, 40(3): 397
5. [5]
  [5] Jiang S X, Feng J J. Chinese Journal of Chromatography (蒋生祥, 冯娟娟. 色谱), 2012, 30(3): 219
6. [6]
  [6] Jelen H H, Zioykowska A, Kaczmarek A. J Agric Food Chem, 2010, 58(24): 12585
7. [7]
  [7] Liu Y, Tang Y F, Song J F, et al. Chinese Journal of Chromatography (刘永, 唐英斐, 宋金凤, 等. 色谱), 2014, 32(2): 139
8. [8]
  [8] Liu W M. [PhD Dissertation]. Dalian: Dalian Institute of Chemical Physics, Chinese Academy of Sciences (刘文民. [博士论文]. 大连: 中国科学院大连化学物理研究所), 2006: 18
9. [9]
  [9] Hu Y L, Fu Y L, Li G K. Anal Chim Acta, 2006, 567: 211
10. [10]
  [10] Zhang W Y, Sun Y, Wu C Y, et al. Anal Chem, 2009, 81: 2912
11. [11]
  [11] Yao G Y, Guan W N, Xu F, et al. Chinese Journal of Chromatography (姚桂燕, 观文娜, 许峰, 等. 色谱), 2008, 26(5): 590
12. [12]
  [12] Mullett W M, Pawliszyn J. Anal Chem, 2002, 74: 1081
13. [13]
  [13] Zhang K G, Hu Y L, Hu Y F, et al. Chinese Journal of Chromatography (张凯歌, 胡玉玲, 胡玉斐, 等. 色谱), 2012, 30(12): 1220
14. [14]
  [14] He X, Li G, Chen H. Inorg Chem Commun, 2002, 5(9): 633
15. [15]
  [15] Liang L L, Ni X L, Zhao Y, et al. Inorg Chem, 2013, 52: 1909
16. [16]
  [16] Ni X L, Xiao X, Cong H, et al. Chem Soc Rev, 2013, 42: 9480
17. [17]
  [17] Liang L L, Zhao Y, Zhang Y Q, et al. CrystEngComm, 2013, 15: 3943
18. [18]
  [18] Zhao Y, Liang L L, Chen K, et al. Dalton Trans, 2014, 43: 929
19. [19]
  [19] Ji N N, Cheng X J, Zhao Y, et al. Inorg Chem, 2014, 53(1): 21
20. [20]
  [20] Lei F F, Huang J Y, Zang X N. Chromatographia, 2011, 74: 99
21. [21]
  [21] Gholivand M B, Abolghasemi M M, Fattahpour P. Chromatographia, 2011, 74: 807
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