Citation: YOU Feiming. Simultaneous determination of six components in hair dyes by ultra performance liquid chromatographytandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2015, 33(1): 17-21. doi: 10.3724/SP.J.1123.2014.09009 shu

Simultaneous determination of six components in hair dyes by ultra performance liquid chromatographytandem mass spectrometry

YOU Feiming ^,

1.
National Center of Processed Foods Quality Supervision and Inspection, Fujian Inspection and Research Institute for Product Quality, Fuzhou 350002, China

Corresponding author: YOU Feiming,
Received Date: 5 September 2014
Available Online: 3 November 2014
Fund Project: 国家质检总局公益性行业科研专项(2012104013-5). (2012104013-5)

A sensitive method was developed for the simultaneous determination of six components which included 4,4'-diaminodiphenylamine sulfate hydrate and 2,4-diaminophenol sulfate, etc. in hair dyes by ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). After extracted by water through ultrasonic extraction, the samples were analyzed by UPLC-MS/MS. The separation was performed on a Waters BEH-C₁₈ column (100 mm×2.1 mm, 1.7 μm) with gradient elution of 10 mmol/L ammonium acetate and acetonitrile. The electrospray ionization (ESI) source in positive ion mode was used for the analysis of the six components in the multiple reaction monitoring (MRM) mode. The results showed good linear relationships with all the correlation coefficients (R²) more than 0.99. The limits of detection (LODs, S/N=3) for the six components were in the range of 0.26-4.6 mg/kg. The average recoveries of the six components in the spiked samples were in the range of 83.0%-92.2% with the relative standard deviations (RSDs, n=6) of 5.4%-11.2%. The precision, accuracy, mean recoveries and the matrix effects satisfied the requirements of cosmetic sample measurement. The proposed method has been applied to the determination of six dyes in actual samples. This method is simple, accurate and effective for the simultaneous determination of the six components in hair dyes.
- ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS),
- dyes,
- hair dyes
1. [1]
  [1] Zhou M. Detergent & Cosmetics (周盟. 日用化学品科学), 2008, 31(9): 6
2. [2]
  [2] Tong Y. Chemical Industry Times (仝毅. 化工时刊), 1999(5): 4
3. [3]
  [3] Zhao X, Wang Y. Guangzhou Chemical Industry (赵鑫, 汪原. 广州化工), 2013, 41(5): 15
4. [4]
  [4] Zhu H J, Yang Y W, Zhu Y. Journal of Environment and Health (朱会卷, 杨艳伟, 朱英. 环境与健康杂志), 2010, 27(6): 513
5. [5]
  [5] Xiao Z Y. China Cosmetics Review (肖子英. 中国化妆品), 2007(9): 90
6. [6]
  [6] Ministry of Health of China. Hygienic Standard for Cosmetics. Beijing: Ministry of Health of People's Republic of China (卫生部. 化妆品卫生规范. 北京: 中华人民共和国卫生部), 2007
7. [7]
  [7] Chen X, Zhang G W. Journal of Nanchang University: Natural Science (陈希, 张国文. 南昌大学学报: 理科版), 2014, 38(2): 143
8. [8]
  [8] Qian X, Jin R N, Zhao L, et al. Academic Journal of Second Military Medical University (钱跹, 金柔男, 赵亮, 等. 第二军医大学学报), 2014, 35(1): 110
9. [9]
  [9] Kang M Q, Li A J, Mu J, et al. Physical Testing and Chemical Analysis Part B: Chemical Analysis (康明芹, 李爱军, 牟峻, 等. 理化检验: 化学分册), 2014, 50(2): 187
10. [10]
  [10] Zhu R, Zhang X L, Wang J D, et al. Physical Testing and Chemical Analysis Part B: Chemical Analysis (朱然, 张旭龙, 王吉德, 等. 理化检验: 化学分册), 2012, 48(5): 526
11. [11]
  [11] Chen Y, Sun J, Li Z, et al. Chinese Journal of Health Laboratory Technology (陈翊, 孙珏, 李正, 等. 中国卫生检验杂志), 2014, 24(6): 779
12. [12]
  [12] Mehmet A, Sevket A. J Pharm Biomed Anal, 2008, 47(1): 68
13. [13]
  [13] Zhong Z X, Li G K, Wu Y H, et al. Anal Chim Acta, 2012, 752(1): 53
14. [14]
  [14] Yoshinori M. J Chromatogr A, 2006, 1108(1): 140
15. [15]
  [15] Yu W L, Zhao K J, Sun X, et al. Physical Testing and Chemical Analysis Part B: Chemical Analysis (于文莲, 赵开径, 孙鑫, 等. 理化检验: 化学分册), 2010, 46(3): 220
16. [16]
  [16] Cao P, Geng J P, Xu H Y, et al. Chinese Journal of Analysis Laboratory (曹鹏, 耿金培, 许红岩, 等. 分析试验室), 2011, 30(10): 59
17. [17]
  [17] Shao C Y, Qin T, Sun D Z, et al. Chinese Journal of Analytical Chemistry (邵超英, 秦婷, 孙多志, 等. 分析化学), 2014, 42(5): 781
1. [1]
  Kun JIANG , Yutong XUE , Kelin LIU , Miao WANG , Tongming SUN , Yanfeng TANG . CeVO₄ hollow microspheres: Fabrication and adsorption performance for dyes. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2229-2236. doi: 10.11862/CJIC.20250223
2. [2]
  Yifan Xie , Liyun Yao , Ruolin Yang , Yuxing Cai , Yujie Jin , Ning Li . Exploration and Practice of Online and Offline Hybrid Teaching Mode in High-Performance Liquid Chromatography Experiment. University Chemistry, 2025, 40(11): 100-107. doi: 10.12461/PKU.DXHX202412133
3. [3]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
4. [4]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
5. [5]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
6. [6]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019
7. [7]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
8. [8]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
9. [9]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034
10. [10]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
11. [11]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
12. [12]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-0. doi: 10.3866/PKU.WHXB202309036
13. [13]
  Qianli Ma , Tianbing Song , Tianle He , Xirong Zhang , Huanming Xiong . Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100106-0. doi: 10.1016/j.actphy.2025.100106
14. [14]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-0. doi: 10.3866/PKU.WHXB202408007
15. [15]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
16. [16]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
17. [17]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
18. [18]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
19. [19]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-0. doi: 10.3866/PKU.WHXB202406020
20. [20]
  Mian Wei , Chang Cheng , Bowen He , Bei Cheng , Kezhen Qi , Chuanbiao Bie . Inorganic-organic CdS/YBTPy S-scheme photocatalyst for efficient hydrogen production and its mechanism. Acta Physico-Chimica Sinica, 2025, 41(12): 100158-0. doi: 10.1016/j.actphy.2025.100158

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(362)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142