Citation: TANG Juan, DING Youchao, CAO Xizhong, QI Yan, QIAN Kai. Rapid detection of eight fluorescent whitening agents in textile by ultra performance convergence chromatography[J]. Chinese Journal of Chromatography, ;2014, 32(11): 1230-1235. doi: 10.3724/SP.J.1123.2014.07030 shu

Rapid detection of eight fluorescent whitening agents in textile by ultra performance convergence chromatography

1.
Inspection Center of Industry Products, Jiangsu Entry-Exit Inspection and Quarantine Bureau, Nanjing 210001, China

Corresponding author: DING Youchao,
Received Date: 18 July 2014
Available Online: 17 August 2014
Fund Project: 国家质检总局科技计划项目(2013IK108). (2013IK108)

An accurate quantitative and confirmative method has been developed for the determination of eight fluorescent whitening agents (FWAs) in textile by ultra performance convergence chromatography (UPC²) coupled with photo diode array (PDA) detection, including 1,2-bis(5-methyl-2-benzoxazole)ethylene (PF), 7-diethylamino-4-methylcoumarin (SWN), 2,2'-(2,5-thiophenediyl)bis(5-(1,1-dimethylethyl)-benzoxazol (OB), 2-[4-[2-[4-(2-benzoxazolyl) phenyl]ethenyl]phenyl]-5-methyl-benzoxazol (KSN), 1,4-bis(2-cyanostyryl)benzene (ER-Ⅰ), 1-(2-cyanostyryl)-4-(4-cyanostyryl)benzene (ER-Ⅱ), 2,2'-(1,4-naphthalenediyl)bis-benzoxazol (KCB), 4,4'-bis[2-(2-methoxyphenyl)ethenyl]-1,1'-biphenyl (FP). The sample was extracted with xylene and concentrated by a rotary evaporator, and then qualitatively and quantitatively analyzed by UPC². The separation of target compounds was achieved on an ACQUITY UPC² HSS C18 SB column (100 mm×3.0 mm, 1.8 μm) by a gradient elution with supercritical carbon dioxide and methanol as mobile phases. External standard method was used for the quantitative determination and the calibration curves showed good linearity in the concentration range of 1.0-20.0 mg/L for the eight target compounds with correlation coefficients not less than 0.9991. The limits of quantification of the eight compounds (LOQs, S/N=10) were 0.70-0.95 mg/L. The average recoveries of the eight compounds ranged from 90.9% to 96.5% at the spiked levels of 2.0, 5.0, 10.0 mg/kg with the relative standard deviations (RSDs) of 2.8%-4.2%. The method is simple, accurate and time-saving with high sensitivity, and can be used for the rapid determination of the eight FWAs in textile.
- ultra performance convergence chromatography (UPC²),
- fluorescent whitening agents (FWAs),
- textile
1. [1]
  [1] Chen R Q. Textile Auxiliaries (陈荣圻. 印染助剂), 2005, 22(7): 1
2. [2]
  [2] Zhang L S, Lu W T, Zhang Y Y. China Science and Technology Review (张丽莎, 卢婉婷, 张永勇. 中国科技博览), 2013(21): 602
3. [3]
  [3] Guo H P, Zhang M Y, Liu Y H. Hunan Papermaking (郭惠萍, 张美云, 刘亚恒. 湖南造纸), 2007(4): 43
4. [4]
  [4] Jiao Y N, Ding L, Zhu S H, et al. Chinese Journal of Chromatography (焦艳娜, 丁利, 朱绍华, 等. 色谱), 2013, 31(1): 83
5. [5]
  [5] Xian Y P, Guo X D, Luo H Y, et al. Chinese Journal of Chromatography (冼燕萍, 郭新东, 罗海英, 等. 色谱), 2013, 31(2): 162
6. [6]
  [6] Liu J, Li J, Li J Z, et al. China Pulp & Paper (刘峻, 李军, 李建中, 等. 中国造纸), 2013, 32(3): 30
7. [7]
  [7] Du Z F, Xian Y P, Liu F J, et al. Chinese Journal of Analytical Chemistry (杜志峰, 冼燕萍, 刘付建, 等. 分析化学), 2014, 42(5): 636
8. [8]
  [8] Chen H C, Ding W H. J Chromatogr A, 2006, 1108: 202
9. [9]
  [9] Chen L S, Jiang D G, Fu W S. Journal of Hygiene Research (陈立松, 蒋定国, 傅武胜. 卫生研究), 2014, 43(1): 152
10. [10]
  [10] Ma H J, Ma Q, Bai H, et al. Chinese Journal of Analysis Laboratory (马会娟, 马强, 白桦, 等. 分析试验室), 2014, 33(5): 569
11. [11]
  [11] Wu Z L, Chen S D, Lin X J, et al. Modern Food Science and Technology (吴钟玲, 陈树东, 林晓佳, 等. 现代食品科技), 2013, 29(11): 2757
12. [12]
  [12] Du Z F, Xian Y P, Liu F J, et al. Modern Food Science and Technology (杜志峰, 冼燕萍, 刘付建, 等. 现代食品科技), 2013, 29(12): 3014
13. [13]
  [13] Aziz A, Steve P, Marie-Noelle P. Chemosphere, 2014, 100: 27
14. [14]
  [14] Shu W C, Ding W H. J Chromatogr A, 2005, 1088: 218
15. [15]
  [15] Chen H C, Wang S P, Ding W H. J Chromatogr A, 2006, 1102: 135
16. [16]
  [16] Li Z H, Wu S B, Liu S S, et al. Chinese Journal of Analytical Chemistry (李中皓, 吴帅宾, 刘珊珊, 等. 分析化学), 2013, 41(12): 1817
17. [17]
  [17] Huang F, Huang X L, Lin X S, et al. Journal of Instrumental Analysis (黄芳, 黄晓兰, 林晓珊, 等. 分析测试学报), 2006, 25(4): 78
18. [18]
  [18] Chen M J, Li Y M, Zhang R, et al. Dyestuffs and Coloration (陈美娟, 李亚明, 张蓉, 等. 染料与染色), 2006, 43(4): 51
1. [1]
  Yifan Xie , Liyun Yao , Ruolin Yang , Yuxing Cai , Yujie Jin , Ning Li . Exploration and Practice of Online and Offline Hybrid Teaching Mode in High-Performance Liquid Chromatography Experiment. University Chemistry, 2025, 40(11): 100-107. doi: 10.12461/PKU.DXHX202412133
2. [2]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
3. [3]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
4. [4]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
5. [5]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
6. [6]
  Shunü Peng , Huamin Li , Zhaobin Chen , Yiru Wang . Simultaneous Application of Multiple Quantitative Analysis Methods in Gas Chromatography for the Determination of Active Ingredients in Traditional Chinese Medicine Preparations. University Chemistry, 2025, 40(10): 243-249. doi: 10.12461/PKU.DXHX202412043
7. [7]
  Cuiping HE , Zhuxuan LI , Yuqing SUN , Jie LIU , Shicheng XU , Zhanchao WU . Ca²⁺ doping induced crystal phase transition and spectral regulation of Ba₃P₄O₁₃: Eu²⁺ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2299-2306. doi: 10.11862/CJIC.20250074
8. [8]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
9. [9]
  Binbin Liu , Yang Chen , Tianci Jia , Chen Chen , Zhanghao Wu , Yuhui Liu , Yuhang Zhai , Tianshu Ma , Changlei Wang . Hydroxyl-functionalized molecular engineering mitigates 2D phase barriers for efficient wide-bandgap and all-perovskite tandem solar cells. Acta Physico-Chimica Sinica, 2026, 42(1): 100128-0. doi: 10.1016/j.actphy.2025.100128
10. [10]
  Jiayao Wang , Guixu Pan , Ning Wang , Shihan Wang , Yaolin Zhu , Yunfeng Li . Preparation of donor-π-acceptor type graphitic carbon nitride photocatalytic systems via molecular level regulation for high-efficient H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(12): 100168-0. doi: 10.1016/j.actphy.2025.100168
11. [11]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
12. [12]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
13. [13]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
14. [14]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
15. [15]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-0. doi: 10.3866/PKU.WHXB202406020
16. [16]
  Mian Wei , Chang Cheng , Bowen He , Bei Cheng , Kezhen Qi , Chuanbiao Bie . Inorganic-organic CdS/YBTPy S-scheme photocatalyst for efficient hydrogen production and its mechanism. Acta Physico-Chimica Sinica, 2025, 41(12): 100158-0. doi: 10.1016/j.actphy.2025.100158
17. [17]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
18. [18]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
19. [19]
  Haoyu Sun , Dun Li , Yuanyuan Min , Yingying Wang , Yanyun Ma , Yiqun Zheng , Hongwen Huang . Hierarchical Palladium-Copper-Silver Porous Nanoflowers as Efficient Electrocatalysts for CO₂ Reduction to C₂₊ Products. Acta Physico-Chimica Sinica, 2024, 40(6): 2307007-0. doi: 10.3866/PKU.WHXB202307007
20. [20]
  Yixuan Wang , Canhui Zhang , Xingkun Wang , Jiarui Duan , Kecheng Tong , Shuixing Dai , Lei Chu , Minghua Huang . Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2305004-0. doi: 10.3866/PKU.WHXB202305004

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(402)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142