Citation: Vanik GHOULIPOUR, Moharram SAFARI. Chromatographic separation of inorganic ions on thin layers of titanium phosphate ion-exchanger[J]. Chinese Journal of Chromatography, ;2014, 32(12): 1373-1379. doi: 10.3724/SP.J.1123.2014.06031 shu

Chromatographic separation of inorganic ions on thin layers of titanium phosphate ion-exchanger

Vanik GHOULIPOUR ^, ,
Moharram SAFARI

1.
Faculty of Chemistry, Kharazmi University, 43 Mofatteh Avenue, Tehran 15719-14911, Iran

Corresponding author: Vanik GHOULIPOUR,
Received Date: 23 June 2014
Available Online: 11 September 2014
Fund Project:

The chromatographic behavior of 30 inorganic cations has been studied on thin layers of titanium phosphate ion-exchanger using several aqueous, organic and mixed mobile phases. The separation of one ion from several other ions and also ternary and binary separations have been developed. Some important analytical separations are reported. The effect of pH of the mobile phase on retention factor (R_f) values of the cations in the presence of complex-forming anion along with the separation power of the ion-exchanger were studied. This ion-exchanger exhibits high sorption capacity and varying selectivity towards metal ions and makes it a suitable stationary phase in thin layer chromatography.
- thin layer chromatography (TLC),
- titanium phosphate,
- separation
1. [1]
  [1] Karger B L, Snyder L R, Horvath C. An Introduction to Separation Science. New York: Wiley, 1973
2. [2]
  [2] Inamuddin, Luqman M. Ion Exchange Technology II. New York: Springer, 2012: 365
3. [3]
  [3] Sherma J. Anal Chem, 2002, 74: 2653
4. [4]
  [4] Qureshi M, Varshney K G. Inorganic Ion Exchangers in Chemical Analysis. Florida: CRC Press, 1991: 231
5. [5]
  [5] Ghoulipour V, Shokri M, Husain S W. Acta Chromatogr, 2011, 23(3): 483
6. [6]
  [6] Ghoulipour V, Shokri M, Husain S W. JPC-J Planar Chromat, 2011, 24 (6): 520
7. [7]
  [7] Ghoulipour V, Amini S, Haghshenas A, et al. JPC-J Planar Chromat, 2010, 23 (4): 250
8. [8]
  [8] Hassankhani-Majd Z, Ghoulipour V, Husain S W. Acta Chromatogr, 2006, 16: 173
9. [9]
  [9] Ravindranath B. Principles and Practice of Chromatography. Chichester: Ellis Horwood, 1989: 372
10. [10]
  [10] Clearfield A, Bortun A I, Khamakov S, et al. Waste Manage, 1998, 18: 203
11. [11]
  [11] Clearfield A, Bortun A I, Bortun L N. Ion-Exchange 11, Development and Applications. Cambridge: Royal Society of Chemistry, 1996
12. [12]
  [12] Ghoulipour V, Husain S W. JPC-J Planar Chromat, 1999, 12: 378
13. [13]
  [13] Ghoulipour V, Husain S W. JPC-J Planar Chromat, 2000, 13: 354
14. [14]
  [14] Ghoulipour V, Husain S W. Anal Sci, 2000, 16: 1079
15. [15]
  [15] Ghoulipour V, Husain S W. Ann Chim-Rome, 2001, 91: 111
16. [16]
  [16] Maheria K, Chundasama U. Indian J Chem, 2007, 46A: 449
17. [17]
  [17] Qureshi M. Handbook of Chromatography: Inorganics. Vol I. Florida: CRC Press, 1987: 19
18. [18]
  [18] Schwedt G. Chromatographic Methods in Inorganic Analysis. Heidelberg: Huthig Verlag, 1981: 71
19. [19]
  [19] Ure A M, Davidson C M. Chemical Separation in the Environment. London: Blackie Academic and Professional Pub, 1995: 1
20. [20]
  [20] Roca S, Airoldi C. J Dalton Trans, 1997, 14: 2517
21. [21]
  [21] Hlavacek V, Puszynski J A. Ind Eng Chem Res, 1996, 35: 349
22. [22]
  [22] Abe M. Inorganic Ion Exchange Material. Florida: CRC Press, 1982: 182
23. [23]
  [23] Horsfall M, Ayebaemi J, Spiff I. Electron J Biotechn, 2005, 8 (2): 162
24. [24]
  [24] Considine D M. Encyclopedia of Chemistry. 4th ed. New York: Van Nostrand Reinhold, 1984: 926
25. [25]
  [25] Holl W H. Ion Exchange Processes: Advances and Applications. Cambridge: Royal Society of Chemistry, 1993: 181
26. [26]
  [26] Maheria K, Chundasama U. J Indian Inst Sci, 2006, 86: 515
27. [27]
  [27] Perrin D D. Stability Constants of Metal-Ion Complexes, Part B: Organic Ligands. Oxford: Pergamon, 1983: 171
28. [28]
  [28] Yatsimirskii K B, Vasilev V P. Instability Constants of Complex Compounds. New York: Consultant Bureau, 1960: 165
29. [29]
  [29] Hogfeldt E. Stability Constants of Metal-Ion Complexes, Part A: Inorganic Ligands. Oxford: Oxford, 1982: 201
30. [30]
  [30] Yatsimirskii K B, Vasilev V P. Instability Constants of Complex Compounds. New York: Consultant Bureau, 1960: 133
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沈阳化工大学材料科学与工程学院沈阳 110142