Citation:
Vanik GHOULIPOUR, Moharram SAFARI. Chromatographic separation of inorganic ions on thin layers of titanium phosphate ion-exchanger[J]. Chinese Journal of Chromatography,
;2014, 32(12): 1373-1379.
doi:
10.3724/SP.J.1123.2014.06031
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The chromatographic behavior of 30 inorganic cations has been studied on thin layers of titanium phosphate ion-exchanger using several aqueous, organic and mixed mobile phases. The separation of one ion from several other ions and also ternary and binary separations have been developed. Some important analytical separations are reported. The effect of pH of the mobile phase on retention factor (Rf) values of the cations in the presence of complex-forming anion along with the separation power of the ion-exchanger were studied. This ion-exchanger exhibits high sorption capacity and varying selectivity towards metal ions and makes it a suitable stationary phase in thin layer chromatography.
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[1]
[1] Karger B L, Snyder L R, Horvath C. An Introduction to Separation Science. New York: Wiley, 1973
-
[2]
[2] Inamuddin, Luqman M. Ion Exchange Technology II. New York: Springer, 2012: 365
- [3]
-
[4]
[4] Qureshi M, Varshney K G. Inorganic Ion Exchangers in Chemical Analysis. Florida: CRC Press, 1991: 231
-
[5]
[5] Ghoulipour V, Shokri M, Husain S W. Acta Chromatogr, 2011, 23(3): 483
-
[6]
[6] Ghoulipour V, Shokri M, Husain S W. JPC-J Planar Chromat, 2011, 24 (6): 520
-
[7]
[7] Ghoulipour V, Amini S, Haghshenas A, et al. JPC-J Planar Chromat, 2010, 23 (4): 250
-
[8]
[8] Hassankhani-Majd Z, Ghoulipour V, Husain S W. Acta Chromatogr, 2006, 16: 173
-
[9]
[9] Ravindranath B. Principles and Practice of Chromatography. Chichester: Ellis Horwood, 1989: 372
-
[10]
[10] Clearfield A, Bortun A I, Khamakov S, et al. Waste Manage, 1998, 18: 203
-
[11]
[11] Clearfield A, Bortun A I, Bortun L N. Ion-Exchange 11, Development and Applications. Cambridge: Royal Society of Chemistry, 1996
-
[12]
[12] Ghoulipour V, Husain S W. JPC-J Planar Chromat, 1999, 12: 378
-
[13]
[13] Ghoulipour V, Husain S W. JPC-J Planar Chromat, 2000, 13: 354
- [14]
-
[15]
[15] Ghoulipour V, Husain S W. Ann Chim-Rome, 2001, 91: 111
-
[16]
[16] Maheria K, Chundasama U. Indian J Chem, 2007, 46A: 449
-
[17]
[17] Qureshi M. Handbook of Chromatography: Inorganics. Vol I. Florida: CRC Press, 1987: 19
-
[18]
[18] Schwedt G. Chromatographic Methods in Inorganic Analysis. Heidelberg: Huthig Verlag, 1981: 71
-
[19]
[19] Ure A M, Davidson C M. Chemical Separation in the Environment. London: Blackie Academic and Professional Pub, 1995: 1
-
[20]
[20] Roca S, Airoldi C. J Dalton Trans, 1997, 14: 2517
-
[21]
[21] Hlavacek V, Puszynski J A. Ind Eng Chem Res, 1996, 35: 349
-
[22]
[22] Abe M. Inorganic Ion Exchange Material. Florida: CRC Press, 1982: 182
-
[23]
[23] Horsfall M, Ayebaemi J, Spiff I. Electron J Biotechn, 2005, 8 (2): 162
-
[24]
[24] Considine D M. Encyclopedia of Chemistry. 4th ed. New York: Van Nostrand Reinhold, 1984: 926
-
[25]
[25] Holl W H. Ion Exchange Processes: Advances and Applications. Cambridge: Royal Society of Chemistry, 1993: 181
-
[26]
[26] Maheria K, Chundasama U. J Indian Inst Sci, 2006, 86: 515
-
[27]
[27] Perrin D D. Stability Constants of Metal-Ion Complexes, Part B: Organic Ligands. Oxford: Pergamon, 1983: 171
-
[28]
[28] Yatsimirskii K B, Vasilev V P. Instability Constants of Complex Compounds. New York: Consultant Bureau, 1960: 165
-
[29]
[29] Hogfeldt E. Stability Constants of Metal-Ion Complexes, Part A: Inorganic Ligands. Oxford: Oxford, 1982: 201
-
[30]
[30] Yatsimirskii K B, Vasilev V P. Instability Constants of Complex Compounds. New York: Consultant Bureau, 1960: 133
-
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