Citation: DAO Xu, LÜ Yibing, TENG Enjiang, ZHANG Linlin, WANG Chao, LI Lihe. Determination of hexavalent chromium in atmospheric particles PM_2.5 and PM₁₀ by ion chromatography with inductively coupled plasma mass spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(9): 936-941. doi: 10.3724/SP.J.1123.2014.05026 shu

Determination of hexavalent chromium in atmospheric particles PM_2.5 and PM₁₀ by ion chromatography with inductively coupled plasma mass spectrometry

DAO Xu ¹ ,
LÜ Yibing ^1,, ,
TENG Enjiang ¹ ,
ZHANG Linlin ¹ ,
WANG Chao ¹ ,
LI Lihe ²

1.
1. China National Environmental Monitoring Centre, Beijing 100012, China;

Corresponding author: LÜ Yibing,
Received Date: 22 May 2014
Available Online: 1 July 2014
Fund Project: 环保公益性行业科研专项课题(201309050). (201309050)

An analytical method using ion chromatography with inductively coupled plasma mass spectrometry (IC-ICP-MS) for the determination of hexavalent chromium (Cr(Ⅵ)) in atmospheric particles PM_2.5 and PM₁₀ was established. The Cr(Ⅵ) in the atmospheric particles was extracted ultrasonically with sodium bicarbonate solution. An anion exchange column (AG7, 50 mm×4 mm) with 75 mmol/L ammonium nitrate solution (containing 0.22 g/L Na₂EDTA, pH 7.0) as mobile phase was used for the separation. ICP-MS was used as a detector for the determination of hexavalent chromium. The calibration curve was linear in the range of 0.05-5 μg/L and the correlation coefficient was 0.9999 for Cr(Ⅵ). The cellulose filter was fit for sampling. With the alkaline cellulose filter, the recovery of Cr(Ⅵ) increased from 75% to 102%. The recovery was complete and stable when the samples were sonicated in 20 mmol/L sodium bicarbonate solution for 30 min. The limit of quantification (LOQ) of Cr(Ⅵ) was 0.0004 ng/m³ when the sampling volume was 20 m³. The average recoveries of Cr(Ⅵ) in the spiked PM_2.5 and PM₁₀ samples ranged from 91.6% to 102% with the relative standard deviations not more than 7.6%. The method is efficient and reliable. It can meet the requirement for the determination of Cr(Ⅵ) in atmospheric particles.
- ion chromatography with inductively coupled plasma mass spectrometry (IC-ICP-MS),
- hexavalent chromium,
- atmospheric particles,
- PM_2.5,
- PM₁₀
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沈阳化工大学材料科学与工程学院沈阳 110142

Determination of hexavalent chromium in atmospheric particles PM2.5 and PM10 by ion chromatography with inductively coupled plasma mass spectrometry

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通讯作者: 陈斌, bchen63@163.com

Determination of hexavalent chromium in atmospheric particles PM_2.5 and PM₁₀ by ion chromatography with inductively coupled plasma mass spectrometry