Citation: WANG Chengyun, ZHANG Weiya, LI Lixia, SHEN Yalei, LIN Junfeng, XIE Tangtang, CHU Naiqing. Determination of residual glycol ethers in leather and leather products by gas chromatography/mass spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(8): 890-896. doi: 10.3724/SP.J.1123.2014.04008 shu

Determination of residual glycol ethers in leather and leather products by gas chromatography/mass spectrometry

1.
Testing and Technology Center for Industrial Products, Shenzhen Entry-Exit Inspection and Quarantine Bureau, Shenzhen 518067, China

Corresponding author: WANG Chengyun,
Received Date: 3 April 2014
Available Online: 3 July 2014
Fund Project: 国家质检总局科研项目(2011IK105) (2011IK105)国家认监委科研制标项目(2013B239k). (2013B239k)

An effective method was established for the simultaneous determination of residual glycol ethers in leather and leather products by gas chromatography/mass spectrometry. Glycol ethers in leather and leather products were ultrasonically extracted at 45℃, using ethyl acetate as the extraction solvent. The extracts were purified by solid phase extraction (SPE) columns, and then analyzed by gas chromatography/mass spectrometry in selected ion monitoring mode. The content of each analyte was calibrated by external standard method. The limit of detection of ethylene glycol ethyl ether (EGEE) was 0.10 mg/kg under the condition of signal to noise (S/N) of 3 and the limits of the other 11 glycol ethers were all less than 0.05 mg/kg. The spiked recoveries varied from 81.2% to 95.5% at three different spiked levels with the relative standard deviations (RSDs) ranged from 1.4% to 6.6%. The proposed method is simple, rapid and accurate, with the limits of detection much less than the requirements of the Regulation Concerning Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) of European Union. It is applicable to the determination of residual glycol ethers in leather and leather products, and provides a reference for the relevant testing standards.
- ultrasonic extraction,
- gas chromatography/mass spectrometry (GC/MS),
- selected ion monitoring (SIM),
- glycol ethers,
- leather
1. [1]
  [1] Takei M, Ando Y, Saitoh W, et al. Toxic Sci, 2010, 118(2): 643
2. [2]
  [2] Decision No. 1348/2008/EC of the European Parliament and of the Council. Official Journal of the European Union, 2008: L348/108
3. [3]
  [3] Commission Decision of 17 December 2008 Amending Decisions 2005/692/EC, 2005/731/EC, 2005/734/EC and 2007/25/EC Concerning Avian Influenza as Regards Their Period of Application. Official Journal of the European Union, 2009: L4/15
4. [4]
  [4] Commission Regulation (EC) No. 552/2009 of 22 June 2009 Amending Regulation (EC) No. 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) as Regards Annex XVII. Official Journal of the European Union, 2009: L164/8
5. [5]
  [5] Wang Z, Han C, You F M, et al. Flavour Fragrance Cosmetics (王征, 韩超, 游飞明, 等. 香精香料化妆品), 2013(5): 24
6. [6]
  [6] Cappiello A, Famiglini G, Palma P, et al. Talanta, 2009, 80(1): 257
7. [7]
  [7] Tran B N, Okoniewski R, Bucciferro A, et al. J AOAC Inter, 2014, 97(1): 232
8. [8]
  [8] Chen J B, Shen R F, Chen H H. Chinese Journal of Health Laboratory (陈金斌, 沈仁富, 陈海红. 中国卫生检验杂志), 2011, 21(9): 2177
9. [9]
  [9] Rahim A A, Saad B, Osman H, et al. Food Chem, 2011, 126: 1412
10. [10]
  [10] Tokarczyk R, Jiang Y, Poole G, et al. J Chromatogr A, 2010, 1217: 6964
11. [11]
  [11] Lian Q Y, Liu G. Quality and Technical Supervision Research (连秋燕, 刘贵. 质量技术监督研究), 2012(6): 12
12. [12]
  [12] Yu B, Tang Y, Zhou X L, et al. Modern Paint & Finishing (于滨, 唐瑛, 周湘玲, 等. 现代涂料与涂装), 2007, 10(3): 47
13. [13]
  [13] Lü Q, Zhang Q, Kang S Y, et al. Journal of Instrumental Analysis (吕庆, 张庆, 康苏媛, 等. 分析测试学报), 2011, 30(7): 776
14. [14]
  [14] Hua J L, Zhang J Y, Xie H Y. Dyeing and Finishing (花金龙, 张建扬, 谢鸿义. 印染), 2012(8): 42
15. [15]
  [15] Chen T, Wen Y Y, Ou Y, et al. Chinese Journal of Chromatography (陈婷, 温裕云, 欧延, 等. 色谱), 2014, 32(1): 89
16. [16]
  [16] Li T B, Liu W, Wang C L, et al. West Leather (李天宝, 刘炜, 王春利, 等. 西部皮革), 2010, 32(23): 32
17. [17]
  [17] Zhao Y, Qi X X. Chinese Journal of Chromatography (赵洋, 戚晓霞. 色谱), 2010, 28(1): 54
18. [18]
  [18] Li Z P, Li L W, Tao M X, et al. Rock and Mineral Analysis (李中平, 李立武, 陶明信, 等. 岩矿测试), 2010, 29(3): 221
19. [19]
  [19] Su J F, Hu C Y, Chen J X, et al. Chinese Journal of Analysis Laboratory (苏建峰, 胡朝阳, 陈劲星, 等. 分析试验室), 2009, 28(6): 84
20. [20]
  [20] Pan X X, Sun S Q, Du Z X, et al. Chinese Journal of Analysis Laboratory (潘晓新, 孙姝琦, 杜振霞, 等. 分析试验室), 2013, 32(7): 52
1. [1]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
2. [2]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
3. [3]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
4. [4]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181
5. [5]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
6. [6]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
7. [7]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
8. [8]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
9. [9]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
10. [10]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
11. [11]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
12. [12]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
13. [13]
  Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . 原位电化学阻抗谱监测长寿命热电池Nb₁₂WO₃₃正极材料的高温双放电机制. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-. doi: 10.1016/j.actphy.2024.100040
14. [14]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
15. [15]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
16. [16]
  Lihui Jiang , Wanrong Dong , Hua Yang , Yongqing Xia , Hongjian Peng , Jun Yuan , Xiaoqian Hu , Zihan Zeng , Yingping Zou , Yiming Luo . Study on Extraction of p-Hydroxyacetophenone. University Chemistry, 2024, 39(11): 259-268. doi: 10.12461/PKU.DXHX202402056
17. [17]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
18. [18]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
19. [19]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
20. [20]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(187)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142