Citation: WANG Miaoyu, YU Hong, LI Ping, LI Jie, GAO Yufeng. Determination of piperidinium ionic liquid cations by ion-pair chromatography-indirect ultraviolet detection[J]. Chinese Journal of Chromatography, ;2014, 32(7): 773-778. doi: 10.3724/SP.J.1123.2014.03036 shu

Determination of piperidinium ionic liquid cations by ion-pair chromatography-indirect ultraviolet detection

1.
College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China

Corresponding author: YU Hong,
Received Date: 24 March 2014
Available Online: 16 April 2014
Fund Project: 黑龙江省教育厅科学技术研究项目(12531192). (12531192)

A method was developed for the determination of piperidinium cations by ion-pair chromatography with indirect ultraviolet detection. Chromatographic separation was performed on a reversed-phase C18 column using background ultraviolet absorption reagent-ion-pair reagent/organic solvent as mobile phase. The effects of the background ultraviolet absorption reagent, detection wavelength, ion-pair reagent, organic solvent, column temperature and flow rate on the determination of piperidinium cations were investigated and the retention rules were studied. The optimized chromatographic conditions for the determination of piperidinium cations were as follows: mobile phase, 0.5 mmol/L 4-aminophenol hydrochloride-0.1 mmol/L 1-heptanesulfonic acid sodium aqueous solution/methanol (80:20, v/v); detection wavelength, 210 nm; column temperature, 30 ℃; flow rate, 1.0 mL/min. Under these conditions, the three piperidinium cations were baseline separated within 4 min. The detection limits (S/N=3) of the piperidinium cations were 0.137-0.545 mg/L. The relative standard deviations (n=5) for peak area and retention time were 0.72% and 0.37% respectively. The method has been successfully applied to the determination of piperidinium cations in ionic liquids synthesized by chemistry laboratory. The recoveries of piperidinium cations after spiking were 97.0%-98.4%. The method is simple, rapid, reproducible, linear, and can meet the quantitative analysis requirement for the determination of piperidinium cations.
- ion-pair chromatography,
- indirect ultraviolet detection,
- piperidinium cations,
- 4-aminophenol hydrochloride
1. [1]
  [1] Studzińska S, Molíková M, Kosobucki P, et al. Chromatographia, 2011, 73(Suppl 1): S35
2. [2]
  [2] Sun X J, Xu J K, Zhao X J, et al. Chromatographia, 2013, 76(15/16): 1013
3. [3]
  [3] Orentiene A, Olsauskaite V, Vickackaite V, et al. Chromatographia, 2011, 73(1/2): 17
4. [4]
  [4] Ru S P, Wu J, Ying Y B, et al. Chinese Journal of Analytical Chemistry (茹柿平, 吴坚, 应义斌, 等. 分析化学), 2012, 40(6): 835
5. [5]
  [5] Qiu H D, Hu Y Y, Liu X, et al. Chinese Journal of Chromatography (邱洪灯, 胡云雁, 刘霞, 等. 色谱), 2007, 25(3): 293
6. [6]
  [6] Qi L, Zhang J, Zhang Z Q. Chinese Journal of Chromatography (亓亮, 张婧, 张志琪. 色谱), 2013, 31(3): 249
7. [7]
  [7] Paszkiewicz M, Stepnowski P. Curr Org Chem, 2011, 15(12): 1873
8. [8]
  [8] Wang P, Guo X F, Jia L H, et al. Chinese Journal of Applied Chemistry (王平, 郭祥峰, 贾丽华, 等. 应用化学), 2013, 30(7): 840
9. [9]
  [9] Zhang S J, Liu X M, Yao X Q, et al. Scientia Sinica Chimica (张锁江, 刘晓敏, 姚晓倩, 等. 中国科学: 化学), 2009, 39(10): 1134
10. [10]
  [10] Han B, Zhang L H, Liang Z, et al. Scientia Sinica Chimica (韩彬, 张丽华, 梁振, 等. 中国科学: 化学), 2010, 40(10): 1487
11. [11]
  [11] Gao W, Yu H, Zhou S. Chinese Journal of Chromatography (高微, 于泓, 周爽. 色谱), 2010, 28(1): 14
12. [12]
  [12] Stojanovic A, Lammerhofer M, Kogelnig D, et al. J Chromatogr A, 2008, 1209(1/2): 179
13. [13]
  [13] Ruiz-Angel M J, Berthod A. J Chromatogr A, 2008, 1189(1/2): 476
14. [14]
  [14] Meng L M, Yu H, Liu Y Z. Chromatographia, 2011, 73(3/4): 367
15. [15]
  [15] Meng L M, Yu H, Huang X, et al. Chinese Journal of Analytical Chemistry (孟令敏, 于泓, 黄旭, 等. 分析化学), 2012, 40(3): 409
16. [16]
  [16] Lamouroux C, Foglia G, Le Rouzo G. J Chromatogr A, 2011, 1218(20): 3022
17. [17]
  [17] Elkady E F, Mahrouse M A. Chromatographia, 2011, 73(3/4): 297
18. [18]
  [18] Mansour F R, Kirkpatrich C L, Danielson N D. Chromatographia, 2013, 76(11/12): 603
19. [19]
  [19] Buszewski B. Anal Bioanal Chem, 2012, 403(5): 1199
20. [20]
  [20] Huang X, Yu H, Dong Y J. Chinese Chem Lett, 2012, 23(7): 843
21. [21]
  [21] Gao W, Yu H. Anal Lett, 2011, 44(5): 922
22. [22]
  [22] Chen Q, Yu H, Meng L M, et al. Journal of Instrumental Analysis (陈倩, 于泓, 孟令敏, 等. 分析测试学报), 2011, 30(1): 38
1. [1]
  Zhiming Feng , Lili Wu , Chengming Wang . Doubly Oxidized Carbene. University Chemistry, 2025, 40(9): 326-331. doi: 10.12461/PKU.DXHX202411008
2. [2]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
3. [3]
  Pingping LU , Shuguang ZHANG , Peipei ZHANG , Aiyun NI . Preparation of zinc sulfate open frameworks based probe materials and detection of Pb²⁺ and Fe³⁺ ions. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 959-968. doi: 10.11862/CJIC.20240411
4. [4]
  Weijie Yang , Mansheng Chen , Chen Xu , Fujian Xu . Hydroxyl-Rich Polycations: Innovative Materials Empowering Life and Health. University Chemistry, 2025, 40(9): 332-343. doi: 10.12461/PKU.DXHX202410072
5. [5]
  Wenjuan Tan , Yong Ye , Xiujuan Sun , Bei Liu , Jiajia Zhou , Hailong Liao , Xiulin Wu , Rui Ding , Enhui Liu , Ping Gao . Building P-Poor Ni₂P and P-Rich CoP₃ Heterojunction Structure with Cation Vacancy for Enhanced Electrocatalytic Hydrazine and Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(6): 2306054-0. doi: 10.3866/PKU.WHXB202306054
6. [6]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
7. [7]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
8. [8]
  Ke Zhao , Zhen Liu , Luyao Liu , Changyuan Yu , Jingshun Pan , Xuguang Huang . Functionalized Reflective Structure Fiber-Optic Interferometric Sensor for Trace Detection of Lead Ions. Acta Physico-Chimica Sinica, 2024, 40(4): 2304029-0. doi: 10.3866/PKU.WHXB202304029
9. [9]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
10. [10]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
11. [11]
  Jia-He Li , Yu-Ze Liu , Jia-Hui Ma , Qing-Xiao Tong , Jian-Ji Zhong , Jing-Xin Jian . 洛芬碱衍生物的合成、化学发光与重金属离子检测. University Chemistry, 2025, 40(6): 230-237. doi: 10.12461/PKU.DXHX202407080
12. [12]
  Lin LI , Le CHEN , Lingjie HOU , Jiaqi JING , Jiayu DING , Tao ZHOU , Ruiping ZHANG . Smartphone-assisted fluorescent silver nanoclusters as ratiometric sensor for visual colorimetric detection of sulfide. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2261-2271. doi: 10.11862/CJIC.20250130
13. [13]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
14. [14]
  Yongqing Kuang , Jie Liu , Jianjun Feng , Wen Yang , Shuanglian Cai , Ling Shi . Experimental Design for the Two-Step Synthesis of Paracetamol from 4-Hydroxyacetophenone. University Chemistry, 2024, 39(8): 331-337. doi: 10.12461/PKU.DXHX202403012
15. [15]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
16. [16]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
17. [17]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
18. [18]
  Yongxin LIU , Xingchen LI , Hongjia LIU , Danni LI , Tao ZHANG , Xi CHEN . Enhancement effect of Fe₃O₄ conversion to MIL-100(Fe) on activation of persulfate for degradation of antibiotic. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2503-2513. doi: 10.11862/CJIC.20250169
19. [19]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
20. [20]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(681)
HTML views(64)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142